Home
Class 12
CHEMISTRY
Assertion (A) Like bromination of benzen...

Assertion (A) Like bromination of benzene, bromination of phenol is also carried out in the presence of Lewis acid.
Reason (R) Lewis acid polarises the bromine molecule.

A

Assertion and reason both are correct and reason is correct explanation of assertion.

B

Assertion and reason both are wrong statements.

C

Assertion is correct statement but reason is wrong statement.

D

Assertion is wrong statement but reason is correct statement.

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to analyze both the assertion (A) and the reason (R) provided in the question. ### Step-by-Step Solution: 1. **Understanding the Assertion (A)**: - The assertion states that "Like bromination of benzene, bromination of phenol is also carried out in the presence of Lewis acid." - In the case of benzene, bromination typically requires a Lewis acid (like FeBr3 or AlBr3) to act as a catalyst. This is because the Lewis acid helps to generate a more electrophilic bromine species, which can then react with the benzene ring. 2. **Understanding the Reason (R)**: - The reason states that "Lewis acid polarizes the bromine molecule." - This is true; the Lewis acid interacts with the bromine molecule, causing polarization. This polarization makes one of the bromine atoms more electrophilic, facilitating the electrophilic aromatic substitution reaction with the benzene or phenol. 3. **Bromination of Phenol**: - Phenol can also undergo bromination, but it is more reactive than benzene due to the presence of the hydroxyl (-OH) group, which is an activating group. - The -OH group donates electron density to the benzene ring, making it more susceptible to electrophilic attack. This means that while bromination of phenol can occur in the presence of a Lewis acid, it is not strictly necessary due to the activating effect of the -OH group. 4. **Conclusion**: - The assertion is incorrect because bromination of phenol does not strictly require a Lewis acid, while the reason is correct as the Lewis acid does polarize the bromine molecule. - Therefore, the correct answer is that the assertion is false, but the reason is true. ### Final Answer: - Assertion (A) is incorrect. - Reason (R) is correct. - The correct option is that the assertion is wrong, but the reason is correct.

To solve the question, we need to analyze both the assertion (A) and the reason (R) provided in the question. ### Step-by-Step Solution: 1. **Understanding the Assertion (A)**: - The assertion states that "Like bromination of benzene, bromination of phenol is also carried out in the presence of Lewis acid." - In the case of benzene, bromination typically requires a Lewis acid (like FeBr3 or AlBr3) to act as a catalyst. This is because the Lewis acid helps to generate a more electrophilic bromine species, which can then react with the benzene ring. ...
Promotional Banner

Topper's Solved these Questions

  • ALDEHYDE, KETONES AND CARBOXYLIC ACIDS

    NCERT EXEMPLAR ENGLISH|Exercise Long Answer Type Questions|4 Videos

Similar Questions

Explore conceptually related problems

Assetion : Permanganate titrations is not carried out in presence of hydrochloric acid. Reason : Hydrochloric acid is oxidised to chlorine.

Which of the following is least likely to behave as Lewis acid?

BCl_(3) behaves as a Lewis acid. Give reason.

Assertion (A) : SN^(1) reaction is carried out in the presence of a plar protic solvent. Reason (R): A polar protic solvent increases the stability of carbocation due to solvation.

Assertion (A) : SN^(2) reaction is carried out in the presence of polar aprotic solvent. Reason (R): Polar aprotic solvents do not contain acidic hydrogen.

Assertion: Iodination of alkanes is carried out in the presence of oxidising agents like HIO_(3) or HNO_(3) . Reason: Iodination of alkanes is an irreversible reaction.

Assertion (A) In presence of enzyme, substrate molecule can be attacked by the reagent effectively. Reason (R) Active sites of enzymes hold the substrate molecule in a suitable position.

(a) Name the starting material used in the industrial preparation of phenol. (b) Write complete reaction for the bromination of phenol in aqueous and non-aqueous medium. (c) Explain why Lewis acid is not required in bromination of phenol ?

In case of bromination to benzene in the presence of FeBr_3 , the electrophile is

NCERT EXEMPLAR ENGLISH-ALCOHOLS, PHENOLS AND ETHERS-All Questions
  1. The carbon-oxygen bond in phenol is slightly stronger than that in met...

    Text Solution

    |

  2. Arrange water, ethanol and phenol in increasing order of acidity and g...

    Text Solution

    |

  3. Match the structures of the compounds given in Column I with the name ...

    Text Solution

    |

  4. Match the starting material given in Column I with the products formed...

    Text Solution

    |

  5. Match the items of Column I with items of Column II.

    Text Solution

    |

  6. Match the items of Column I with items of Column II.

    Text Solution

    |

  7. Assertion (A) Addition reaction of water to but-1-ene in acidic medium...

    Text Solution

    |

  8. Assertion (A) p-nitrophenol is more acidic than phenol. Reason (R) N...

    Text Solution

    |

  9. Assertion (A) IUPAC name of the compound CH(3)-underset(CH(3))unders...

    Text Solution

    |

  10. Assertion (A) Bond angle is ethers is slightly less than tetrahedral a...

    Text Solution

    |

  11. Assertion (A) Boiling points of alcohols and ethers are high. Reason...

    Text Solution

    |

  12. Assertion (A) Like bromination of benzene, bromination of phenol is al...

    Text Solution

    |

  13. Assertion (A) o-nitrophenol is less soluble in water than the m and p-...

    Text Solution

    |

  14. Assertion (A) Ethanol is a weaker acid than phenol. Reason (R) Sodiu...

    Text Solution

    |

  15. Assertion (A) Phenol forms 2, 4, 6-tribromophenol o treatment with Br(...

    Text Solution

    |

  16. Assertion (A) Phenols give o-and p-nitrophenol on nitration with conc....

    Text Solution

    |

  17. Write the mechanism of the reaction of HI with methoxybenzene.

    Text Solution

    |

  18. (a) Name the starting material used in the industrial preparation of p...

    Text Solution

    |

  19. How can phenol be converted to aspirin ?

    Text Solution

    |

  20. Explain a process in which a biocatalyst is used industrial preparatio...

    Text Solution

    |