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Dipole-dipole forces act between the mol...

Dipole-dipole forces act between the molecules possessing permanent dipole. Ends of dipoles possess 'partial charges'. The partial charge is

A

more than unit electronic charge

B

equal to unit electronic charge

C

less than unit electronic charge

D

double the unit electronic charge

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The correct Answer is:
**Step-by-Step Solution:** 1. **Understanding Dipole-Dipole Forces:** - Dipole-dipole forces occur between molecules that have permanent dipoles. A permanent dipole arises when there is a significant difference in electronegativity between the atoms in a molecule, leading to an uneven distribution of electron density. 2. **Identifying Partial Charges:** - In a molecule like water (H₂O), the oxygen atom is more electronegative than the hydrogen atoms. This results in the oxygen atom acquiring a partial negative charge (δ-) and the hydrogen atoms acquiring partial positive charges (δ+). 3. **Defining Partial Charges:** - Partial charges (δ+ and δ-) are not full charges like the charge of an electron (approximately -1.6 x 10⁻¹⁹ coulombs). Instead, they represent a fraction of the full charge due to the unequal sharing of electrons. 4. **Comparing Partial Charges to Electronic Charge:** - Since partial charges arise from the difference in electronegativity and the sharing of electrons, they are typically much smaller than the charge of a single electron. Therefore, we conclude that the magnitude of partial charges is less than the unit electronic charge. 5. **Final Conclusion:** - Based on the above reasoning, the answer to the question is that the partial charge is less than the unit electronic charge. **Answer: The partial charge is less than the unit electronic charge.** ---

**Step-by-Step Solution:** 1. **Understanding Dipole-Dipole Forces:** - Dipole-dipole forces occur between molecules that have permanent dipoles. A permanent dipole arises when there is a significant difference in electronegativity between the atoms in a molecule, leading to an uneven distribution of electron density. 2. **Identifying Partial Charges:** - In a molecule like water (H₂O), the oxygen atom is more electronegative than the hydrogen atoms. This results in the oxygen atom acquiring a partial negative charge (δ-) and the hydrogen atoms acquiring partial positive charges (δ+). ...
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Knowledge Check

  • Assertion : Dipole - dipole forces acting between the molecules possessing permanent dipole , are weaker than ion - ion interactions . Reason : The attractive forces decrease with the increase of distance between the dipoles .

    A
    If both assertion and reason are true and reason is the correct explanation of assertion .
    B
    If both assertion and reason are true but reason is not the correct explanation of assertion .
    C
    If assertion is true but reason is false .
    D
    If both assertion and reason are false .
  • Which one of the following molecules does not possess a permanent electric dipole moment?

    A
    `H_2 S `
    B
    `SO_2`
    C
    `CS_2`
    D
    `SO_3`
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