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Consider the isoelectronic species, Na^(...

Consider the isoelectronic species, `Na^(+),Mg^(2+),F^(-)` and `O^(2-)`. The correct order of increasing length of their radii is:

A

`F^(-) lt O^(2-) lt Mg^(2+) lt Na^(+)`

B

`Mg^(2+) lt Na^(+) lt F^(-) lt O^(2-)`

C

`O^(2-) lt F^(-) lt Na^(+) lt Mg^(2+)`

D

`O^(2-) lt F^(-) lt Mg^(2+) lt Na^(+)`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the correct order of increasing length of the radii for the isoelectronic species \( \text{Na}^+, \text{Mg}^{2+}, \text{F}^-, \text{O}^{2-} \), we can follow these steps: ### Step 1: Identify the Number of Electrons All the species are isoelectronic, meaning they all have the same number of electrons. Let's calculate the number of electrons for each ion: - **Na\(^+\)**: Sodium has an atomic number of 11. Losing 1 electron gives it \( 11 - 1 = 10 \) electrons. - **Mg\(^{2+}\)**: Magnesium has an atomic number of 12. Losing 2 electrons gives it \( 12 - 2 = 10 \) electrons. - **F\(^-\)**: Fluorine has an atomic number of 9. Gaining 1 electron gives it \( 9 + 1 = 10 \) electrons. - **O\(^{2-}\)**: Oxygen has an atomic number of 8. Gaining 2 electrons gives it \( 8 + 2 = 10 \) electrons. ### Step 2: Compare the Number of Protons Next, we need to determine the number of protons in each ion, as the effective nuclear charge will influence the ionic radius: - **Na\(^+\)**: 11 protons - **Mg\(^{2+}\)**: 12 protons - **F\(^-\)**: 9 protons - **O\(^{2-}\)**: 8 protons ### Step 3: Analyze the Effective Nuclear Charge The effective nuclear charge (Z_eff) is the net positive charge experienced by electrons in a multi-electron atom. The more protons present, the stronger the attraction on the electrons, leading to a smaller radius. - **Mg\(^{2+}\)**: 12 protons (strongest attraction, smallest radius) - **Na\(^+\)**: 11 protons (next strongest attraction) - **F\(^-\)**: 9 protons (weaker attraction) - **O\(^{2-}\)**: 8 protons (weakest attraction, largest radius) ### Step 4: Order the Ions by Radius Based on the analysis of the effective nuclear charge, we can order the ions from smallest to largest radius: 1. **Mg\(^{2+}\)** (smallest) 2. **Na\(^+\)** 3. **F\(^-\)** 4. **O\(^{2-}\)** (largest) ### Final Answer The correct order of increasing length of their radii is: \[ \text{Mg}^{2+} < \text{Na}^+ < \text{F}^- < \text{O}^{2-} \]

To determine the correct order of increasing length of the radii for the isoelectronic species \( \text{Na}^+, \text{Mg}^{2+}, \text{F}^-, \text{O}^{2-} \), we can follow these steps: ### Step 1: Identify the Number of Electrons All the species are isoelectronic, meaning they all have the same number of electrons. Let's calculate the number of electrons for each ion: - **Na\(^+\)**: Sodium has an atomic number of 11. Losing 1 electron gives it \( 11 - 1 = 10 \) electrons. - **Mg\(^{2+}\)**: Magnesium has an atomic number of 12. Losing 2 electrons gives it \( 12 - 2 = 10 \) electrons. - **F\(^-\)**: Fluorine has an atomic number of 9. Gaining 1 electron gives it \( 9 + 1 = 10 \) electrons. ...
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