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Discuss and compare the trend in ionisat...

Discuss and compare the trend in ionisation enthalpy of the elements of group 1 with those of group 17 elements.

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### Step-by-Step Solution 1. **Identify the Groups**: - Group 1 elements: Lithium (Li), Sodium (Na), Potassium (K), Rubidium (Rb), Cesium (Cs). - Group 17 elements: Fluorine (F), Chlorine (Cl), Bromine (Br), Iodine (I). 2. **Define Ionization Enthalpy**: - Ionization enthalpy is the energy required to remove an electron from an isolated gaseous atom. It is a measure of how strongly an atom holds onto its electrons. 3. **Factors Affecting Ionization Enthalpy**: - The ionization enthalpy depends on the atomic size and the effective nuclear charge (Z_eff) experienced by the outermost electron. - Smaller atomic size and higher Z_eff lead to higher ionization enthalpy. 4. **Trends in Group 1 Elements**: - Group 1 elements are characterized by larger atomic sizes as you move down the group (Li < Na < K < Rb < Cs). - As the atomic size increases, the outermost electron is further from the nucleus, resulting in a lower Z_eff. - Consequently, the ionization enthalpy decreases down the group. 5. **Trends in Group 17 Elements**: - Group 17 elements (the halogens) have smaller atomic sizes compared to group 1 elements (F < Cl < Br < I). - As you move down the group, the atomic size increases, but the halogens still have higher ionization enthalpy values than group 1 elements due to their smaller size and higher Z_eff. 6. **Comparison of Ionization Enthalpy**: - Group 1 elements have lower ionization enthalpy compared to group 17 elements because: - Group 1 elements are larger, leading to a lower Z_eff. - Group 17 elements are smaller and have a higher Z_eff, making it more difficult to remove an electron. - Thus, the trend shows that ionization enthalpy for group 1 elements is less than that of group 17 elements. 7. **Conclusion**: - In summary, the ionization enthalpy of group 1 elements decreases down the group, while group 17 elements have higher ionization enthalpy values due to their smaller size and higher effective nuclear charge.

### Step-by-Step Solution 1. **Identify the Groups**: - Group 1 elements: Lithium (Li), Sodium (Na), Potassium (K), Rubidium (Rb), Cesium (Cs). - Group 17 elements: Fluorine (F), Chlorine (Cl), Bromine (Br), Iodine (I). 2. **Define Ionization Enthalpy**: - Ionization enthalpy is the energy required to remove an electron from an isolated gaseous atom. It is a measure of how strongly an atom holds onto its electrons. ...
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