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In which of the following compounds, an ...

In which of the following compounds, an elements exhibits two different oxidation states?

A

`NH_(2)OH`

B

`NH_(4)NO_(3)`

C

`N_(2)H_(4)`

D

`N_(3)H`

Text Solution

AI Generated Solution

The correct Answer is:
To determine in which of the given compounds an element exhibits two different oxidation states, we will analyze the oxidation states of nitrogen in each compound provided in the options. ### Step-by-Step Solution: 1. **Identify the Compounds**: We are given four nitrogen-containing compounds to analyze. Let's denote them as: - (1) NH2OH (Hydroxylamine) - (2) Ammonium Nitrate (NH4NO3) - (3) N2H4 (Hydrazine) - (4) N3H (Azide) 2. **Calculate Oxidation State for NH2OH**: - Let the oxidation state of nitrogen be \( X \). - The oxidation state of hydrogen is +1 (4 hydrogen atoms contribute +4). - The hydroxyl group (OH) has a charge of -1. - The overall charge of the molecule is 0. - Thus, we set up the equation: \[ X + 4 - 1 = 0 \implies X = -1 \] - Therefore, nitrogen in NH2OH has an oxidation state of -1. 3. **Calculate Oxidation State for Ammonium Nitrate (NH4NO3)**: - For the ammonium ion (NH4+): - Let the oxidation state of nitrogen be \( X \). - The equation becomes: \[ X + 4 - 1 = 0 \implies X = -3 \] - For the nitrate ion (NO3-): - Let the oxidation state of nitrogen be \( Y \). - The equation becomes: \[ Y - 6 = -1 \implies Y = +5 \] - Thus, nitrogen in ammonium exhibits -3 and in nitrate exhibits +5. This means nitrogen in ammonium nitrate has two different oxidation states. 4. **Calculate Oxidation State for N2H4**: - Let the oxidation state of nitrogen be \( X \). - The equation becomes: \[ 2X + 4 = 0 \implies 2X = -4 \implies X = -2 \] - Both nitrogen atoms in N2H4 have the same oxidation state of -2. 5. **Calculate Oxidation State for N3H**: - Let the oxidation state of nitrogen be \( Z \). - The equation becomes: \[ 3Z + 1 = 0 \implies 3Z = -1 \implies Z = -\frac{1}{3} \] - All three nitrogen atoms in N3H have the same oxidation state of -1/3. 6. **Conclusion**: - From the calculations, we find that only in ammonium nitrate (NH4NO3) does nitrogen exhibit two different oxidation states: -3 in the ammonium ion and +5 in the nitrate ion. - Therefore, the answer is **Ammonium Nitrate (NH4NO3)**. ### Final Answer: The compound in which an element exhibits two different oxidation states is **Ammonium Nitrate (NH4NO3)**.

To determine in which of the given compounds an element exhibits two different oxidation states, we will analyze the oxidation states of nitrogen in each compound provided in the options. ### Step-by-Step Solution: 1. **Identify the Compounds**: We are given four nitrogen-containing compounds to analyze. Let's denote them as: - (1) NH2OH (Hydroxylamine) - (2) Ammonium Nitrate (NH4NO3) - (3) N2H4 (Hydrazine) ...
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