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The largest oxidation number exhibited b...

The largest oxidation number exhibited by an element depends on its outer eletronic configuration. With which of the following outer electronic configurations the element will exhibit largest oxidation number ?

A

`3d^(2)4s^(2)`

B

`3d^(3)4s^(2)`

C

`3d^(5)4s^(1)`

D

`3d^(5)4s^(2)`

Text Solution

AI Generated Solution

The correct Answer is:
To determine which outer electronic configuration allows an element to exhibit the largest oxidation number, we need to analyze the given configurations based on the number of d and s electrons they contain. ### Step-by-Step Solution: 1. **Identify the given electronic configurations**: - Option 1: 3d² 4s² - Option 2: 3d³ 4s² - Option 3: 3d⁵ 4s¹ - Option 4: 3d⁵ 4s² 2. **Understand the concept of oxidation number**: - The maximum oxidation state of a transition metal can be calculated using the formula: \[ \text{Maximum Oxidation State} = (n-1)d + ns \] where \( n \) is the principal quantum number of the outermost shell. 3. **Calculate the maximum oxidation state for each configuration**: - **Option 1 (3d² 4s²)**: \[ \text{Maximum Oxidation State} = 2 (from \, 3d) + 2 (from \, 4s) = 4 \] - **Option 2 (3d³ 4s²)**: \[ \text{Maximum Oxidation State} = 3 (from \, 3d) + 2 (from \, 4s) = 5 \] - **Option 3 (3d⁵ 4s¹)**: \[ \text{Maximum Oxidation State} = 5 (from \, 3d) + 1 (from \, 4s) = 6 \] - **Option 4 (3d⁵ 4s²)**: \[ \text{Maximum Oxidation State} = 5 (from \, 3d) + 2 (from \, 4s) = 7 \] 4. **Compare the maximum oxidation states**: - Option 1: 4 - Option 2: 5 - Option 3: 6 - Option 4: 7 5. **Conclusion**: - The configuration with the largest maximum oxidation state is **Option 4 (3d⁵ 4s²)**, which can exhibit an oxidation number of 7. ### Final Answer: The element with the outer electronic configuration **3d⁵ 4s²** will exhibit the largest oxidation number, which is **7**.

To determine which outer electronic configuration allows an element to exhibit the largest oxidation number, we need to analyze the given configurations based on the number of d and s electrons they contain. ### Step-by-Step Solution: 1. **Identify the given electronic configurations**: - Option 1: 3d² 4s² - Option 2: 3d³ 4s² - Option 3: 3d⁵ 4s¹ ...
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