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Assertion (A) : The decomposition of hyd...

Assertion (A) : The decomposition of hydrogen peroxide to form water and oxygen is an example of disproportionation reaction
Reason (R) : The oxygen of peroxide is in `-1` oxidation state and it is converted to zero oxidation state in `O_(2)` and `-2` oxidation state in `H_(2)O`.

A

Both A and R are true and R is the correct explanation of A

B

Both A and R are true but R is not the correct explanation of A

C

A is true but R is false

D

Both A and R are false

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to analyze both the assertion and the reason provided. ### Step-by-Step Solution: 1. **Understanding the Assertion**: - The assertion states that the decomposition of hydrogen peroxide (H₂O₂) to form water (H₂O) and oxygen (O₂) is an example of a disproportionation reaction. - A disproportionation reaction is one in which the same species is both oxidized and reduced. 2. **Identifying the Reaction**: - The decomposition reaction can be written as: \[ 2 H_2O_2 \rightarrow 2 H_2O + O_2 \] - Here, hydrogen peroxide decomposes into water and oxygen. 3. **Assigning Oxidation States**: - In hydrogen peroxide (H₂O₂): - The oxidation state of hydrogen (H) is +1. - The oxidation state of oxygen (O) in H₂O₂ is -1 (since it is a peroxide). - In water (H₂O): - The oxidation state of hydrogen (H) is +1. - The oxidation state of oxygen (O) is -2. - In molecular oxygen (O₂): - The oxidation state of oxygen (O) is 0 (elemental form). 4. **Analyzing Changes in Oxidation States**: - The oxygen in H₂O₂ changes from -1 to: - -2 in H₂O (reduction) - 0 in O₂ (oxidation) - Thus, one part of the oxygen is reduced (gaining electrons) and another part is oxidized (losing electrons). 5. **Conclusion on Disproportionation**: - Since the same element (oxygen) is undergoing both oxidation and reduction in the reaction, it qualifies as a disproportionation reaction. - Therefore, the assertion is true. 6. **Understanding the Reason**: - The reason states that the oxygen in hydrogen peroxide is in the -1 oxidation state and it is converted to 0 in O₂ and -2 in H₂O. - This statement is accurate as we have established the oxidation states correctly. 7. **Final Evaluation**: - Both the assertion and the reason are true. - The reason correctly explains the assertion. ### Final Answer: Both the assertion (A) and the reason (R) are true, and the reason is the correct explanation for the assertion. Therefore, the answer is **1**.

To solve the question, we need to analyze both the assertion and the reason provided. ### Step-by-Step Solution: 1. **Understanding the Assertion**: - The assertion states that the decomposition of hydrogen peroxide (H₂O₂) to form water (H₂O) and oxygen (O₂) is an example of a disproportionation reaction. - A disproportionation reaction is one in which the same species is both oxidized and reduced. ...
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