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Moleular hydrides are classified as ele...

Moleular hydrides are classified as electron deficient, electron precise and electron rich compounds. Explain each type with two examples.

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To classify molecular hydrides into three categories—electron deficient, electron precise, and electron rich—let's explore each type in detail along with two examples for each. ### Step 1: Electron Deficient Hydrides - **Definition**: Electron deficient hydrides are those in which the central atom has an incomplete octet. This means that the central atom does not have enough electrons to complete its octet, making it electron deficient. - **Formation**: These hydrides are typically formed by elements from Group 13 of the periodic table. - **Examples**: 1. **Boron Hydride (BH3)**: Boron has three valence electrons and forms three bonds with hydrogen atoms, resulting in only six electrons around it. Thus, it has an incomplete octet. 2. **Aluminum Hydride (AlH3)**: Similar to boron, aluminum has three valence electrons and forms three bonds with hydrogen, also resulting in an incomplete octet with only six electrons. ### Step 2: Electron Precise Hydrides - **Definition**: Electron precise hydrides have the exact number of electrons required to form normal covalent bonds, meaning they have a complete octet. - **Formation**: These hydrides are typically formed by elements from Group 14 of the periodic table. - **Examples**: 1. **Methane (CH4)**: Carbon has four valence electrons and forms four bonds with hydrogen, resulting in a complete octet with eight electrons around it. 2. **Silane (SiH4)**: Silicon, like carbon, has four valence electrons and forms four bonds with hydrogen, achieving a complete octet. ### Step 3: Electron Rich Hydrides - **Definition**: Electron rich hydrides contain excess electrons, which are often present as lone pairs on the central atom. These hydrides can donate these lone pairs, making them act as Lewis bases. - **Formation**: These hydrides are typically formed by elements from Groups 15, 16, and 17 of the periodic table. - **Examples**: 1. **Ammonia (NH3)**: Nitrogen has five valence electrons and forms three bonds with hydrogen, leaving one lone pair of electrons, making it electron rich. 2. **Water (H2O)**: Oxygen has six valence electrons and forms two bonds with hydrogen, leaving two lone pairs of electrons, making it electron rich. ### Summary - **Electron Deficient Hydrides**: BH3, AlH3 (incomplete octet) - **Electron Precise Hydrides**: CH4, SiH4 (complete octet) - **Electron Rich Hydrides**: NH3, H2O (excess electrons as lone pairs)

To classify molecular hydrides into three categories—electron deficient, electron precise, and electron rich—let's explore each type in detail along with two examples for each. ### Step 1: Electron Deficient Hydrides - **Definition**: Electron deficient hydrides are those in which the central atom has an incomplete octet. This means that the central atom does not have enough electrons to complete its octet, making it electron deficient. - **Formation**: These hydrides are typically formed by elements from Group 13 of the periodic table. - **Examples**: 1. **Boron Hydride (BH3)**: Boron has three valence electrons and forms three bonds with hydrogen atoms, resulting in only six electrons around it. Thus, it has an incomplete octet. 2. **Aluminum Hydride (AlH3)**: Similar to boron, aluminum has three valence electrons and forms three bonds with hydrogen, also resulting in an incomplete octet with only six electrons. ...
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NCERT EXEMPLAR ENGLISH-HYDROGEN-SHORT ANSWER TYPE QUESTIONS
  1. What do you undersetand by the term auto-protolysis of water ? What ...

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  2. Dicuss briefly de- mineralistion of water by ion exchange resin.

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  3. Moleular hydrides are classified as electron deficient, electron prec...

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  4. How is heavy water prepared? Compare its physical properties with ...

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  5. Write one chemical reactions for the preparation of D(2)O(2).

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  6. Calculate the strenght of 5 volumes H(2)O(2) solution.

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  7. (i) Draw the gas phase and solid phase structure of H(2)O(2). (ii...

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  8. Melting point, enthaply of vaporisation and visvocsity data of H(2...

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  9. Dihydrogen reacts with dioxygen (O(2)) to from water .Write the na...

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  10. Explain why HCl is a gas and HF is a liquid ?

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  11. When the first element of the periodic table is treated with diox...

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  12. Rohan heard that instructions were given to the laboratory attend...

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  13. Given reason why hydrogen resembles alkali metals ?

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  14. Hydrogen generally form covalent compounds. Give reason

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  15. Why is the ionisation enthalpy of hydrogen higher than that of sod...

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  16. Basic principle of hydrogen economy is transportation and storage of...

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  17. What is the importance of heavy water ?

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  18. Write the Lewis structure of hydrogen peroxide .

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  19. An acidic solution of hydrogen peroxide behaves as an oxidising ...

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  20. With the help of suitable examples, explain the property of H(2)O(2...

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