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Give a method for the manufacture of ...

Give a method for the manufacture of hydrogen peroxide and explain the reactions involved therein .
(ii) Illustrate oxidising, reducing and acidic properties of hydrogen peroxide with equations.

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### Step-by-Step Solution #### Part (i): Manufacture of Hydrogen Peroxide 1. **Starting Material**: The manufacture of hydrogen peroxide (H2O2) can be initiated using **2-ethyl anthraquinone** as the primary starting material. 2. **Oxidation Reaction**: In the process, 2-ethyl anthraquinone undergoes an oxidation reaction to form hydrogen peroxide. This reaction can be represented as: \[ \text{2-ethyl anthraquinone} + \text{O}_2 \rightleftharpoons \text{H}_2\text{O}_2 + \text{oxidized products} \] Here, oxygen (O2) is used to oxidize the anthraquinone, producing hydrogen peroxide and some other oxidized by-products. 3. **Water Removal**: The produced hydrogen peroxide typically contains about 1% water. This water is removed through a process of extraction. 4. **Concentration**: The hydrogen peroxide solution is then concentrated to approximately 30% by mass using **distillation**. 5. **Purification**: Further purification is achieved by distilling the solution at low pressure to obtain a more concentrated hydrogen peroxide solution, typically around 85%. #### Part (ii): Properties of Hydrogen Peroxide 1. **Oxidizing Agent in Acidic Medium**: - Reaction: \[ 2 \text{Fe}^{2+} + 2 \text{H}^+ + \text{H}_2\text{O}_2 \rightarrow 2 \text{Fe}^{3+} + 2 \text{H}_2\text{O} \] - Explanation: In this reaction, hydrogen peroxide acts as an oxidizing agent, converting ferrous ions (Fe²⁺) to ferric ions (Fe³⁺) in an acidic medium. 2. **Reducing Agent in Acidic Medium**: - Reaction: \[ \text{HOCl} + \text{H}_2\text{O}_2 \rightarrow \text{H}_3\text{O}^+ + 2 \text{OH}^- \] - Explanation: Here, hydrogen peroxide acts as a reducing agent, reducing hypochlorous acid (HOCl) to hydronium ions (H₃O⁺) and hydroxide ions (OH⁻). 3. **Oxidizing Agent in Basic Medium**: - Reaction: \[ \text{Mn}^{2+} + \text{H}_2\text{O}_2 + 2 \text{OH}^- \rightarrow \text{MnO}_4^- + 2 \text{H}_2\text{O} \] - Explanation: In a basic medium, hydrogen peroxide oxidizes manganese ions (Mn²⁺) to permanganate ions (MnO₄⁻). 4. **Reducing Agent in Basic Medium**: - Reaction: \[ \text{I}_2 + \text{H}_2\text{O}_2 + 2 \text{OH}^- \rightarrow 2 \text{I}^- + 2 \text{H}_2\text{O} + \text{O}_2 \] - Explanation: In this reaction, hydrogen peroxide acts as a reducing agent, converting iodine (I₂) to iodide ions (I⁻) while releasing oxygen gas (O₂) in a basic medium.

### Step-by-Step Solution #### Part (i): Manufacture of Hydrogen Peroxide 1. **Starting Material**: The manufacture of hydrogen peroxide (H2O2) can be initiated using **2-ethyl anthraquinone** as the primary starting material. 2. **Oxidation Reaction**: In the process, 2-ethyl anthraquinone undergoes an oxidation reaction to form hydrogen peroxide. This reaction can be represented as: \[ ...
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