Home
Class 12
CHEMISTRY
State kohlraush law of independent migra...

State kohlraush law of independent migration ions. Why does the conductivity of a solution decrease with dilution?

Text Solution

Verified by Experts

Kohlrausch law of independent migration of ions: The molar conductivity of an electrolyte at infinite dilution is the sum of the individual contributions of the anion and cation of he electrolye `lambda_(m)(CH_(3)COOH)=lambdaCH_(3)COO^(-)+lamdba_(H)^(+)`
Promotional Banner

Topper's Solved these Questions

  • XII BOARDS

    XII BOARD PREVIOUS YEAR PAPER ENGLISH|Exercise Outside Delhi : SET-II|13 Videos
  • XII BOARDS

    XII BOARD PREVIOUS YEAR PAPER ENGLISH|Exercise Outside Delhi : SET-III|13 Videos
  • XII BOARDS

    XII BOARD PREVIOUS YEAR PAPER ENGLISH|Exercise C.B.S.E. CLASS - XII|30 Videos
  • SAMPLE PAPER 2019

    XII BOARD PREVIOUS YEAR PAPER ENGLISH|Exercise SECTION: D|1 Videos

Similar Questions

Explore conceptually related problems

Why does the conductivity of a solution decreases with dilution ?

State Kohlrausch law of independent migration of ions. Write an expression for the molar conductivity of acetic acid at infinite dilution according to Kohlrausch law. {:((b),"Calculate",:,wedge^(@)m" for acetic acid."),(,"Given that",:,wedge^(@)m(HCl)=426 " S " "cm"^(2)mol^(-1)),(,,,wedge^(@) m(NaCl)=126 " S " cm^(2) mol^(-1)),(,,,wedge^(@) m(CH_(3)COONa)=91 " S " cm^(2)mol^(-1)):}

State Mendel's law of Independent assortment.

State Kohlrausch's Law for the independent migration of ions. Mention the applications of the Law.

How can Kohlrausch's law of independent migration can be applied for calculating the degree of dissociation (alpha) of weak electrolytes ?

Statement-I: Molar conductivity of a weak electrolyte at infinite dilution cannot be determined experimenttally. Because Statement-II: Kohlrausch law help to find the moar conductivity of a weak electrolyte at infinite dilution.

(a) Apply Kohlrausch law of independent migration of ions, write the expression to determine the limiting molar conductivity of calcium chloride. (b) Given are the conductivity and molar conductivity of NaCI solutions at 298 K at different concentrations : Compare the variation of conductivity and molar conductivity of NaCI solutions on dilution. Give reason. (c) 0.1 M KCI solution offered a resistance of 100 ohms in conductivity cell at 298 K. If the cell constant of the cell is 1.29 cm^(-1) , calculate the molar conductivity of KCI solution.

STATEMENT 1 Using koihlrausch's law of independent migration of ions it is possible to calculate wedge^(@) for anyelectrolyte form the lambda^(@) of individual ions STATEMENT 2 : Limiting molar molar conductivity of na electrolyte can be repersented as the sum of hte individual contribution of the anion and cation of hte electrolyte STATEMENT 3: When concentration appraches zero molar conductivity reaches the lowest limit

Explain why does conductivity of germainum crystals increase on doping with galium ?

Assertion (A) : The ration of specific conductivity to the observed conductance does not depend upon the concentration of the solution taken in the conductivity cell. Reason (R) : Specific conductivity decreases with dilution whereas observed conductance increases with the dilution.

XII BOARD PREVIOUS YEAR PAPER ENGLISH-XII BOARDS-Outside Delhi : SET-I
  1. (i) What type of non stichiometirc point defect is responsible for the...

    Text Solution

    |

  2. How will you distinguish between the following pairs of terms: (i) T...

    Text Solution

    |

  3. State kohlraush law of independent migration ions. Why does the conduc...

    Text Solution

    |

  4. For chemical reaction R rarr P the variation in the concentration (R )...

    Text Solution

    |

  5. Explain the principle of the method electrolytic refining of metal. Gi...

    Text Solution

    |

  6. Complete the following equations:

    Text Solution

    |

  7. Draw the structure of the following : (i) XeF(2) (ii) BrF(3)

    Text Solution

    |

  8. Write the equation involved in the following reaction : (i) Reimer -...

    Text Solution

    |

  9. Write mechanism of the following reaction: CH(3)CH(2)OHoverset(HBr)t...

    Text Solution

    |

  10. Write the name of the monomers used for getting the following polymer ...

    Text Solution

    |

  11. (a) Calculate Delta(r)G^(@) for the reaction Mg(s)+Cu^(2)(aq)rarrMg^(2...

    Text Solution

    |

  12. What are emulsions ? What are their different types ? Give an example ...

    Text Solution

    |

  13. Give reasons for the following (i) (CH(3))(3) P=0 exists but (CH(3))...

    Text Solution

    |

  14. (i) Write the IUPAC name of the complex [Cr(NH(3))(4)Cl(2)Cl What ty...

    Text Solution

    |

  15. (a) Draw the structures of major monohola prodcuts in each of the foll...

    Text Solution

    |

  16. Account for the following (i)Primary amines (R-NH(2)) have higher b...

    Text Solution

    |

  17. Give the structers of A,B and C in the following reaction : (i) C(6)...

    Text Solution

    |

  18. Defines the following as related to proteins: (i)Peptide linkage (...

    Text Solution

    |

  19. Dr . Rajiv Mishra is working against the post of a senior doctor in a ...

    Text Solution

    |

  20. (a) Define the following terms: (i) Molarity (ii) Molal elevation ...

    Text Solution

    |