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Give reasons for the following : (a) M...

Give reasons for the following :
(a) Measurement of osmotic pressure method is preferred for the determination of molar masses of macromolecules such as proteins and polymers .
(b) Aquatic animals are more comfortable in cold water than in warm water.

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Measurement of osmotic pressure method is preferred for the determination of molar masses of macromolecules such as proteins and polymers because this method has the advantage that is use molarities instead of molalities . Secondly , the changes observed in these properties are very small . On the other hand , osmotic pressures of the order of `10^(-3)` atm . can be easily measured in term of mm.
(b) Aquatic species need dissolved oxygen for breathing . As solubility of gases decreases with increase of temperature , less oxygen is available in summer in the lakes . Hence , they feel more comfortable in winter when the solubility is high .
(c) KCl , being an electrolyte , dissociates almost completely to give `K^(+)` and `Cl^(-)` ions whereas glucose being non-electrolyte , does not dissociate . Hence , number of particles in 1M KCl solution is nearly double than in 1M sugar solution . Elevation of boiling point , being a colligative property is therefore , nearly twice for KCl solution than for glucose solution of same molarity .
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The main application of osmotic pressure measurement is in the determination of the molar mass of a substance which is either slightly soluble or has a very high molar mass such as proteins, polymers of various types and colloids.This is due to the fact that even a very small concentraion of the solution produces fairly large magnitude of osomotic pressure.In the laboratory the concentrations usually employed are of the order of 10^(-3) to 10^(-4) M.At concentration of 10^(-3) mol dm^(-3) , the magnitude of osmotic pressure of 300 K is : P=10^(-3)xx0.082xx300=0.0246 atm or 0.0246xx1.01325xx10^5=2492.595 Pa At this concentration, the values of other colligative properties such as boiling point elevation and depression in freezing point are too small to be determined experimentally. Further polymers have following two types of molar masses : (A) Number average molar mass (barM_n) , which is given by (undersetisumN_iM_i)/(undersetisumN_i) where N_i is the number of molecules having molar mass M_i . (B) Molar average molar mass (barM_m) , which is given by (undersetisumN_iM_i^2)/(undersetisumN_iM_i) Obviously the former is independent of the individual characteristics of the molecules and gives equal weightage to large and small molecules in the polymer sample.On the other hand later gives more weightage to the heavier molecules.Infact with the help of a colligative property only one type of molar mass of the polymer can be determined. One gram each of polymer A (molar mass=2000) and B(molar mass=6000) is dissolved in water to form one litre solution at 27^@C .The osmotic pressure of this solution will be :

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The osomotic pressure pi depends on the molar concentration of the solution (pi=CRT) . If two solutions are of equal solute concentration and, hence, have the same omotic pressure, they are said to be isotonic. If two solutions are of unequal osmotic pressures, the more concentrated solution is said to be hypertonic and the more diluted solution is described as hypotonic. Osmosis is the major mechanism for transporting water upward in the plants. Answer the following questions: Osmotic rise of a solution depends on

The osomotic pressure pi depends on the molar concentration of the solution (pi=CRT) . If two solutions are of equal solute concentration and, hence, have the same omotic pressure, they are said to be isotonic. If two solutions are of unequal osmotic pressures, the more concentrated solution is said to be hypertonic and the more diluted solution is described as hypotonic. Osmosis is the major mechanism for transporting water upward in the plants. Answer the following questions: A plant cell shrinks when it is kept in:

The osomotic pressure pi depends on the molar concentration of the solution (pi=CRT) . If two solutions are of equal solute concentration and, hence, have the same omotic pressure, they are said to be isotonic. If two solutions are of unequal osmotic pressures, the more concentrated solution is said to be hypertonic and the more diluted solution is described as hypotonic. Osmosis is the major mechanism for transporting water upward in the plants. Answer the following questions: What would be the percent strength of solution of urea that would be isotonic with 4.5% solution of glucose?

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