Home
Class 12
CHEMISTRY
Write the cell reaction and calculate th...

Write the cell reaction and calculate the e.m.f. of the following cell at 298 K :
Sn(s) `|Sn^(2+) (0.004M)||H^(+) (0.020M) |H_(2)(g)` (1 bar )| Pt(s)
(Given `E_(Sn^(2+)//Sn)^(@) = -0.14V`).

Text Solution

AI Generated Solution

To solve the problem, we will follow these steps: ### Step 1: Identify the half-reactions In the given cell: - The anode reaction (oxidation) involves tin (Sn) being oxidized to tin ions (Sn²⁺). - The cathode reaction (reduction) involves hydrogen ions (H⁺) being reduced to hydrogen gas (H₂). **Anode Reaction:** ...
Promotional Banner

Topper's Solved these Questions

  • XII BOARDS

    XII BOARD PREVIOUS YEAR PAPER ENGLISH|Exercise OUTSIDE DELHI (SET-I)|35 Videos
  • XII BOARDS

    XII BOARD PREVIOUS YEAR PAPER ENGLISH|Exercise Set I|31 Videos
  • XII BOARDS

    XII BOARD PREVIOUS YEAR PAPER ENGLISH|Exercise General Instrucations|31 Videos
  • SAMPLE PAPER 2019

    XII BOARD PREVIOUS YEAR PAPER ENGLISH|Exercise SECTION: D|1 Videos

Similar Questions

Explore conceptually related problems

Write the Nernst equation and compute the e.m.f. of the following cell at 298K: Sn(s)"|"Sn^(2+)(0.05M)"||"H^(+)(0.02M)"|"H_(2) , 1 atm Pt [Given : E^(Theta)Sn^(2+)//Sn=-0.136V ]

Calculate the e.m.f. of the following cell at 298K : Pt(s)|Br_(2)(l)|Br^(-)(0.010M)||H^(+)(0.030M)|H_(2)(g)(1"bar")|Pt(s) Given : E_((1)/(2)Br_(2)//Br^(-))^(@)=+1.08V .

Calculate the emf of the following cell at 298K : Fe(s) abs(Fe^(2+)(0.001M))abs(H^+(1M))H_2(g) (1"bar"),Pt(s) ( "Give E_("Cell")^@ = +0.44V )

Write the Nernst equation and EMF of the following cells at 298K : a. Mg(s)|Mg^(2+)(0.001M)||Cu^(2+)(0.0001M)|Cu(s) b. Fe(s)|Fe^(2+)(0.001M)||H^(o+)(1M)|H_(2)(g)(1 ba r)|Pt(s) c. Sn(s)|Sn^(2+)(0.050M)||H^(o+)(0.020M)|H_(2)(g)(1 ba r)|Pt(s) d. Pt(s)|Br_(2)(1)|Br^(-)(0.010M)||H^(o+)(0.030M)|H_(2)(g)(1 ba r)|Pt(s)

Mark the correct Nernst equation for the given cell. F_((s))|Fe^(2+)(0.001 M) ||H^(+)(1M) | H_(2(g)) ( 1 bar ) | Pt_((s)) is

(a) The e.m.f. of the following cell at 298 K is 0.1745 V Fe(s) //Fe^(2+) (0.1 M) ////H^(+)(x M)//H_(2)(g) ("1 bar")//Pt (s) Given : E_(Fe^(2+)//Fe)^(0) = - 0.44 V Calculate the H^(+) ions concentration of the solution at the electrode where hydrogen is being produced. (b) Aqueous solution of copper sulphate and silver nitrate are electrolysed by 1 ampere current for 10 minutes in separate electrolytic cells. Will the mass of copper and silver deposited on the cathode be same or different? Explain your answer.

Calculate the cell potential of following cell Pt(s)|H_(2)(g)"(0.1 bar)"|BOH(0.1M)||HA(0.1M)|H_(2)(g)("1 bar")|Pt Given K_(a)(HA)=10^(-7), K_(b)(BOH)=10^(-5)

(a) A cell is prepared by dipping a zinc rod in 1M zinc sulphate solution and a silver electrode in 1M silver nitrate solution. The standard electrode potential given : E^(@)Zn_(2+1//Zn) = -0.76V, E^(@)A_(g+//)A_(g) = +0.80V What is the effect of increase in concentration of Zn^(2+) " on the " E_(cell) ? (b) Write the products of electrolysis of aqueous solution of NaCI with platinum electrodes. (c) Calculate e.m.f. of the following cell at 298 K: "Ni(s)"//"Ni"^(2+)(0.01M)////"Cu"^(2+)(0.1M)//"Cu(s)" ["Given"E_(Ni2+//Ni)^(@) = -0.025 V E_(Cu2+//Cu)^(@) = +0.34V] Write the overall cell reaction.

Calculate the emf of the following cell reaction at 298 K: Mg(s) +Cu^(2+) (0.0001 M) to Mg^(2+) (0.001M) +Cu(s) The standard potential (E^(Theta)) of the cell is 2.71 V.

Calculate the cell e.m.f. and DeltaG for the cell reaction at 298K for the cell. Zn(s) | Zn^(2+) (0.0004M) ||Cd^(2+) (0.2M)|Cd(s) Given, E_(Zn^(2+)//Zn)^(@) =- 0.763 V, E_(Cd^(+2)//Cd)^(@) = - 0.403 V at 298K . F = 96500 C mol^(-1) .

XII BOARD PREVIOUS YEAR PAPER ENGLISH-XII BOARDS-Questions
  1. Account for the following : (a) Aromatic carboxylic acids do not und...

    Text Solution

    |

  2. Complete and balance the following chemical equations : (a) Fe^(2+) ...

    Text Solution

    |

  3. Give reasons for the following : (a) Measurement of osmotic pressure...

    Text Solution

    |

  4. An element 'X' (At. Mass = 40 g mol^(-1)) having f.c.c structure has u...

    Text Solution

    |

  5. A first order reaction is 50% completed in 40 minutes at 300 K and in ...

    Text Solution

    |

  6. What happens when : (a) freshly prepared precipitate of Fe(OH)(3) is...

    Text Solution

    |

  7. Write the chemical reaction involved in the extraction of gold by cyan...

    Text Solution

    |

  8. Give reason for the folloiwng : (a) E("value")^(@) for Mn^(3+)//Mn^(...

    Text Solution

    |

  9. (a) Identify the chiral molecule in the following pair : (b) Writ...

    Text Solution

    |

  10. (A), (B) and (C ) are three non-cylic funtional isomers of a carbonyl ...

    Text Solution

    |

  11. (a) Why is bithional added to soap ? (b) What is tincture of iodine ...

    Text Solution

    |

  12. Define the following with an example of each : (a) Polysaccharides ...

    Text Solution

    |

  13. (a) Write the product when D-glucose reacts with conc. HNO(3). (b) A...

    Text Solution

    |

  14. Write the formula of the following coordination compound : Iron (III) ...

    Text Solution

    |

  15. Shyam went to a grocery shop to purchase some food items. The shopkeep...

    Text Solution

    |

  16. (a) Give reasons : (i) H(3)PO(3) undergoes disproportionation react...

    Text Solution

    |

  17. (a) When concentrated sulphuric acid was added to an unknown salt pres...

    Text Solution

    |

  18. Write the cell reaction and calculate the e.m.f. of the following cell...

    Text Solution

    |

  19. (a)For the reaction : 2AgCl (s) + H(2)(g) (1 atm) to 2 Ag(s) + 2H^...

    Text Solution

    |

  20. (a) Write the reactions involved in the following : (i) Hofmann brom...

    Text Solution

    |