Home
Class 12
CHEMISTRY
Following data are obtained for the reac...

Following data are obtained for the reaction:
`N_(2)O_(5) rarr 2NO_(2) + .^(1//2) O_(2)`
`|{:(t//s,0,300,600),([N_(2)O_(5)]//mol L^(-1),1.6 xx 10^(-2),0.8 xx 10^(-2),0.4 xx 10^(-2)):}|`
(a) Show that it follows first order reaction
(b) Calculate the half-life
(Given log 2 = 0.3010 log 4 = 0.6021]

Text Solution

AI Generated Solution

To solve the problem, we will follow these steps: ### Step 1: Determine if the reaction follows first-order kinetics 1. **Write the first-order rate equation:** For a first-order reaction, the rate constant \( k \) can be calculated using the formula: \[ k = \frac{1}{t} \ln \left( \frac{[A_0]}{[A_t]} \right) ...
Promotional Banner

Topper's Solved these Questions

  • XII BOARDS

    XII BOARD PREVIOUS YEAR PAPER ENGLISH|Exercise Set II|10 Videos
  • XII BOARDS

    XII BOARD PREVIOUS YEAR PAPER ENGLISH|Exercise Set III|21 Videos
  • XII BOARDS

    XII BOARD PREVIOUS YEAR PAPER ENGLISH|Exercise OUTSIDE DELHI (SET-I)|35 Videos
  • SAMPLE PAPER 2019

    XII BOARD PREVIOUS YEAR PAPER ENGLISH|Exercise SECTION: D|1 Videos

Similar Questions

Explore conceptually related problems

For the first order reaction 2N_(2)O_(5)(g) rarr 4NO_(2)(g) + O_(2)(g)

For the reaction N_(2)O_(5) rarr 2NO_(2) + (1)/(2) O_(2) , the rate of disappearance of N_(2)O_(5) is 6.25 xx 10^(-3) "mol L"^(-1) s^(-1) . The rate of formation of NO_(2) and O_(2) will be respectively.

The rate constant for the reaction, 2N_(2)O_(5) rarr 4NO_(2) + O_(2) is 3.0 xx 10^(-5) s^(-1) . If the rate is 2.40 xx 10^(-5) mol L^(-1) s^(-1) , then the initial concentration of N_(2)O_(5) (in mol L^(-1) ) is

For a reaction 2NO(g) + 2H_(2)(g) rarr N_(2)(g)+2H_(2)O(g) the following data were obtained: |{:(,[NO] (mol L^(-1)),[H_(2)] (mol L^(-1)),"Rate" (mol L^(-1) s^(-1))),(1.,5 xx 10^(-3),2.5 xx 10^(-3),3 xx 10^(-5)),(2.,15 xx 10^(-3),2.5 xx 10^(-3),9xx10^(-5)),(3.,15 xx 10^(-3),10 xx 10^(-3),3.6 xx 10^(-4)):}| (a) Calculating the order of reactions. (b) Find the rate constant. (c ) Find the initial rate if [NO] = [H_(2)] = 8.0 xx 10^(-3) M

The experiment data for the reaction 2A + B_(2) rarr 2AB is |{:("Experiment",[A] M,[B_(2)] M,"Initial rate" (mol L^(-1) s^(-1)),),(I,0.50,0.5,1.6 xx 10^(-4),),(II,0.50,1.0,3.2 xx 10^(-4),),(III,1.00,1.0,3.2 xx 10^(-4),):}| Write the most probable rate equation for the reaction giving reason for your answer.

The experiment data for the reaction 2A + B_(2) rarr 2AB is |{:("Experiment",[A] M,[B_(2)] M,"Initial rate" (mol L^(-1) s^(-1)),),(I,0.50,0.5,1.6 xx 10^(-4),),(II,0.50,1.0,3.2 xx 10^(-4),),(III,1.00,1.0,3.2 xx 10^(-4),):}| Write the most probable rate equation for the reacting giving reason for you answer.

The initial concentration of N_(2)O_(5) in the following first order reaction: N_(2)O_(5)(g) rarr 2NO_(2)(g)+(1)/(2)O_(2)(g) was 1.24 xx 10^(-2) mol L^(-1) at 318 K . The concentration of N_(2)O_(5) after 60 min was 0.20 xx 10^(-2) mol L^(-1) . Calculate the rate constant of the reaction at 318 K .

For the reaction equilibrium, N_2O_4 (g) hArr 2NO_2 (g) the concentrations of N_2O_4 and NO_2 at equilibrium are 4.8 xx 10^(-2) and 1.2 xx 10 ^(-2) " mol " L^(-1) respectively . The value of K_c for the reaction is

For the reaction 2N_(2)O_(5)(g) to 4NO_(2) (g) + O_(2)(g) , the rate of formation of NO_(2)(g) is 2.8 xx 10^(-3) Ms^(-1) . Calculate the rate of disapperance of N_(2)O_(5)(g) .

The following data were obtained during the first thermal decompoistion of N_(2)O_(5) (g) at constant volume. 2N_(2)O_(5) (g) rarr 2N_(2)O_(4) (g)+O_(2)(g) |{:("S.No.","Time (s)","Total pressure (atm)"),(i.,0,0.5),(ii.,100,0.512):}| Calculate the rate constant.

XII BOARD PREVIOUS YEAR PAPER ENGLISH-XII BOARDS-Set I
  1. A 10% solution (by mass) of sucrose in water has freezing point of 26...

    Text Solution

    |

  2. (a) Calculate the mass of Ag deposited at cathode when a current of 2 ...

    Text Solution

    |

  3. (i) What type of isomerism is shown by the complex [Co(NH(3))(6)] [Cr(...

    Text Solution

    |

  4. Write one difference in each of the following: (i) Lyophobic sol and...

    Text Solution

    |

  5. Following data are obtained for the reaction: N(2)O(5) rarr 2NO(2) +...

    Text Solution

    |

  6. Following compounds are given to you : 2-Bromopentane, 2-Bromo-2-met...

    Text Solution

    |

  7. (a) Write the principle of method used for the refining of germanium ...

    Text Solution

    |

  8. Write structures of compounds A,B and C in each of the following react...

    Text Solution

    |

  9. Do the following conversions in not more than two steps: (i) Benzoic...

    Text Solution

    |

  10. Write the structure of the monomers used for getting the following pol...

    Text Solution

    |

  11. Define the following : (i) Anionic detergents (ii) Broad spectrum ...

    Text Solution

    |

  12. Given reasion: (i) Thermal stability decreases from H(2)O " to " H(2...

    Text Solution

    |

  13. Give reasons for the following (a) Acetylation of aniline reduces it...

    Text Solution

    |

  14. After watching a programme on TV about the presence of carcinogens (ca...

    Text Solution

    |

  15. (a) Account for the following : (i) Transition metals form large num...

    Text Solution

    |

  16. (a) (i) How is the variability in oxidation states of transition metal...

    Text Solution

    |

  17. (a) An element has atomic mass 93 g mol^(1) and density 11.5 g cm^(-3)...

    Text Solution

    |

  18. (a) Calculate the number of unit cells in 8.1g of aluminium if it crys...

    Text Solution

    |

  19. Given simple chemical tests to distinguish between the following pairs...

    Text Solution

    |

  20. Write the formula of reagents used in the following reactions: (i) B...

    Text Solution

    |