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Explain the following observation : ...

Explain the following observation :
In the structure of `HNO_(3)` the N-O bond (121 pm) is shorter than the N-OH bond (140 pm).

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To explain the observation that the N-O bond in HNO₃ (121 pm) is shorter than the N-OH bond (140 pm), we can analyze the structure and bonding characteristics of nitric acid. ### Step-by-Step Solution: 1. **Understanding the Structure of HNO₃**: - HNO₃, or nitric acid, has a molecular structure that includes nitrogen (N) bonded to three oxygen (O) atoms. Among these, one oxygen is bonded to a hydrogen atom (OH group), while the other two are involved in double bonds with nitrogen. 2. **Resonance Structures**: ...
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Explain the following situations : (i) In the structure of HNO_(3) molecule , the N-O bond (121 pm) is shorter than N-OH bond (140pm). (ii) SF_(4) is easily hydrolysed whereas SF_(6) is not easily hydrolysed. (iii) XeF_(2) has a straight linear structure and not a bent angular structure.

How would you account for the following : (i) H_(2)S is acidic than H_(2)O . (ii) The N-O bond in NO_(2)^(-) is shorter than the N-O bond in NO_(3)^(-) . (iii) Both O_(2) and F_(2) stabilize high oxidation states but the ability of oxygen to stabilize the higher oxidation state exceeds that of flurine.

The H-N-H bond angle in NH_3 is greater than the H-As-H bond angle in AsH_3 .

Why is O-O bond length in ozone (128 pm) more than in O_2 (122 pm)?

Give reason for : (i) SF_6 is kinetically an inert substance. (ii) The N - O bond in N0_(2)^- is shorter than the N - O bond in NO_(3)^- .

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