An alkane cannot be chlorinated by using which of the following reagents?

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An alkane cannot be chlorinated by using which of the fallowing reagents ?

From an alcohol molecule, the hydroxyl group cannot be replaced by using the following reagents :

Which of the following cannot form Grignard reagent

Chlorine cannot be used :

Which of the following cannot reduce Tollen's reagent?

Which of the following alkane cannot show isomerism?