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A sample of 16 g charcoal was brought in...

A sample of 16 g charcoal was brought into contact with `CH_(4)` gas contained in a vessel of 1 litre at `27^(@) C` . The presses of gas was found to fall from 760 to 608 torr. The density of chacoal sample is `1.6 g//m^(3)` . What is the volume of the `CH_(4)` gas adsorbed per gram of the adsorbent at 608 torr and `27^(@)C`?

A

`125 L/g`

B

`16.25 mL/g`

C

`26 mL/g `

D

none of these

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to determine the volume of CH₄ gas adsorbed per gram of charcoal at a pressure of 608 torr and a temperature of 27°C. Here’s a step-by-step solution: ### Step 1: Calculate the initial volume of CH₄ gas at 760 torr Using the ideal gas law, we can find the volume of gas at the initial pressure (P₁ = 760 torr) and the volume of the vessel (V = 1 L). \[ V_1 = 1 \, \text{L} = 1000 \, \text{mL} \] ### Step 2: Calculate the final volume of CH₄ gas at 608 torr Using the formula for the relationship between pressure and volume (Boyle's Law), we can find the final volume (V₂) of the gas when the pressure drops to 608 torr: \[ P_1 \cdot V_1 = P_2 \cdot V_2 \] Substituting the known values: \[ 760 \, \text{torr} \cdot 1000 \, \text{mL} = 608 \, \text{torr} \cdot V_2 \] Now, solving for V₂: \[ V_2 = \frac{760 \cdot 1000}{608} \approx 1250 \, \text{mL} \] ### Step 3: Calculate the volume of charcoal To find the volume occupied by the charcoal, we can use its mass and density. The density of charcoal is given as 1.6 g/cm³. \[ \text{Volume of charcoal} = \frac{\text{mass}}{\text{density}} = \frac{16 \, \text{g}}{1.6 \, \text{g/cm}^3} = 10 \, \text{cm}^3 = 10 \, \text{mL} \] ### Step 4: Calculate the volume of CH₄ gas adsorbed The volume of CH₄ gas adsorbed can be calculated by subtracting the volume occupied by the charcoal from the final volume of the gas: \[ \text{Volume of gas adsorbed} = V_2 - \text{Volume of charcoal} = 1250 \, \text{mL} - 10 \, \text{mL} = 1240 \, \text{mL} \] ### Step 5: Calculate the volume of CH₄ gas adsorbed per gram of charcoal Now we can find the volume of CH₄ gas adsorbed per gram of charcoal: \[ \text{Volume of gas adsorbed per gram} = \frac{\text{Volume of gas adsorbed}}{\text{mass of charcoal}} = \frac{1240 \, \text{mL}}{16 \, \text{g}} = 77.5 \, \text{mL/g} \] ### Final Answer The volume of CH₄ gas adsorbed per gram of charcoal at 608 torr and 27°C is **77.5 mL/g**. ---
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