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If a is the initial concentration of the...

If `a` is the initial concentration of the rectant, the half life period of the reaction of `n^(th)` order is inversely proportional to :

A

`a^(n-1)`

B

`a^(n)`

C

`a^(1-n)`

D

`a^(n+1)`

Text Solution

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The correct Answer is:
To solve the question regarding the half-life period of a reaction of nth order, we need to analyze the relationship between the half-life period (T_half) and the initial concentration of the reactant (a). ### Step-by-Step Solution: 1. **Understanding Half-Life in Chemical Reactions**: The half-life period (T_half) is the time required for the concentration of a reactant to decrease to half of its initial value. The relationship between half-life and the order of the reaction is important. 2. **Formulas for Half-Life**: - For a **zero-order reaction** (n = 0): \[ T_{1/2} = \frac{a}{2k} \] Here, T_half is directly proportional to the initial concentration (a). - For a **first-order reaction** (n = 1): \[ T_{1/2} = \frac{0.693}{k} \] In this case, T_half does not depend on the initial concentration (a). 3. **General Formula for nth Order Reaction**: For a reaction of order n, the half-life can be expressed as: \[ T_{1/2} \propto \frac{1}{a^{n-1}} \] This indicates that the half-life period is inversely proportional to the initial concentration raised to the power of (n-1). 4. **Conclusion**: From the general formula, we can conclude that the half-life period (T_half) of a reaction of nth order is inversely proportional to \( a^{n-1} \). Therefore, the correct answer to the question is that T_half is inversely proportional to \( a^{n-1} \). ### Final Answer: The half-life period of the reaction of nth order is inversely proportional to \( a^{n-1} \).
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