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In the body centered cubic unit cell and...

In the body centered cubic unit cell and simple unit cell, the radius of atoms in terms of edge length (a) of the unit cell is respectively:

A

(a) `(a)/(2), (a)/(2sqrt(2))`

B

(b) ` (a)/(sqrt(2)),(a)/(2)`

C

(c) ` (a)/(2sqrt(2)),(a)/(2)`

D

(d) ` (3sqrt(a))/(4),(a)/(2)`

Text Solution

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The correct Answer is:
To find the radius of atoms in terms of the edge length (a) of the unit cell for both the simple cubic unit cell and the body-centered cubic (BCC) unit cell, we can follow these steps: ### Step-by-Step Solution: 1. **Understanding the Simple Cubic Unit Cell:** - In a simple cubic unit cell, atoms are located at each of the eight corners of the cube. - Each corner atom contributes \( \frac{1}{8} \) of an atom to the unit cell. - Therefore, the total number of atoms per unit cell (Z) is: \[ Z = 8 \times \frac{1}{8} = 1 \] 2. **Finding the Relationship Between Radius and Edge Length in Simple Cubic:** - In a simple cubic structure, the atoms touch each other along the edge of the cube. - The edge length \( a \) is equal to twice the radius \( r \) of the atom: \[ a = 2r \] - From this, we can express the radius in terms of the edge length: \[ r = \frac{a}{2} \] 3. **Understanding the Body-Centered Cubic (BCC) Unit Cell:** - In a BCC unit cell, there are atoms at each of the eight corners and one atom at the center of the cube. - The total number of atoms per unit cell (Z) is: \[ Z = 8 \times \frac{1}{8} + 1 = 2 \] 4. **Finding the Relationship Between Radius and Edge Length in BCC:** - In a BCC structure, the atoms touch along the body diagonal of the cube. - The length of the body diagonal \( d \) is given by: \[ d = \sqrt{3}a \] - Along the body diagonal, there are 4 radii (since there are two atoms, one at each end and one in the center): \[ d = 4r \] - Therefore, we can set the two expressions for the body diagonal equal to each other: \[ \sqrt{3}a = 4r \] - Solving for \( r \): \[ r = \frac{\sqrt{3}}{4}a \] ### Final Results: - For the simple cubic unit cell: \[ r = \frac{a}{2} \] - For the body-centered cubic unit cell: \[ r = \frac{\sqrt{3}}{4}a \]
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