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The elements crystallizes in a body cent...

The elements crystallizes in a body centered cubic lattice and the edge of the unit cell is 0.351nm. The density is `0.533g//cm^(3)`. What is the atomic mas?

A

12

B

6.94

C

9.01

D

10.8

Text Solution

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The correct Answer is:
To find the atomic mass of the element that crystallizes in a body-centered cubic (BCC) lattice, we can use the formula for density in relation to the unit cell parameters. Here’s a step-by-step solution: ### Step 1: Understand the relationship between density, mass, and volume The formula for density (ρ) is given by: \[ \rho = \frac{Z \cdot M}{V} \] where: - \( \rho \) = density (g/cm³) - \( Z \) = number of atoms per unit cell - \( M \) = molar mass (g/mol) - \( V \) = volume of the unit cell (cm³) ### Step 2: Identify parameters for BCC For a body-centered cubic (BCC) lattice: - \( Z = 2 \) (there are 2 atoms per unit cell) ### Step 3: Calculate the volume of the unit cell The volume \( V \) of the unit cell can be calculated using the edge length \( a \): \[ V = a^3 \] Given that the edge length \( a = 0.351 \, \text{nm} = 0.351 \times 10^{-7} \, \text{cm} \): \[ V = (0.351 \times 10^{-7} \, \text{cm})^3 = 4.33 \times 10^{-22} \, \text{cm}^3 \] ### Step 4: Substitute values into the density formula Now, substituting the known values into the density formula: \[ 0.533 = \frac{2 \cdot M}{4.33 \times 10^{-22}} \] ### Step 5: Solve for M (molar mass) Rearranging the equation to solve for \( M \): \[ M = \frac{0.533 \cdot 4.33 \times 10^{-22}}{2} \] Calculating \( M \): \[ M = \frac{0.533 \cdot 4.33 \times 10^{-22}}{2} = 1.15 \times 10^{-22} \, \text{g/mol} \] ### Step 6: Convert to a more usable unit To find the molar mass in grams per mole, we need to multiply by Avogadro's number \( (6.022 \times 10^{23} \, \text{mol}^{-1}) \): \[ M = 1.15 \times 10^{-22} \cdot 6.022 \times 10^{23} = 6.93 \, \text{g/mol} \] ### Final Answer The atomic mass of the element is approximately **6.93 g/mol**. ---
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