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If the ratio of coordination no. of A to...

If the ratio of coordination no. of A to that iof B is x:y, then the ratio of no. of atoms of A to that no, of atoms of B in the unit cell is

A

x:y

B

y:x

C

`x^(2):y`

D

`y:x^(2)`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to find the ratio of the number of atoms of A to the number of atoms of B in a unit cell, given the ratio of their coordination numbers. ### Step-by-Step Solution: 1. **Understand Coordination Number**: - The coordination number (CN) of an atom in a crystal structure is the number of nearest neighboring atoms surrounding it. - In this case, we are given that the coordination number of A is \( x \) and that of B is \( y \). 2. **Set Up the Relationship**: - Since the coordination number of A is \( x \), it means that each atom of A is surrounded by \( x \) atoms of B. - Similarly, since the coordination number of B is \( y \), each atom of B is surrounded by \( y \) atoms of A. 3. **Express Number of Atoms**: - Let’s denote the number of atoms of A in the unit cell as \( n_A \) and the number of atoms of B as \( n_B \). - From the coordination numbers, we can express: - The number of atoms of A in terms of B: \( n_A = n \cdot y \) (where \( n \) is a constant). - The number of atoms of B in terms of A: \( n_B = n \cdot x \). 4. **Formulate the Ratio**: - Now, we can find the ratio of the number of atoms of A to the number of atoms of B: \[ \frac{n_A}{n_B} = \frac{n \cdot y}{n \cdot x} = \frac{y}{x} \] 5. **Final Result**: - Therefore, the ratio of the number of atoms of A to the number of atoms of B in the unit cell is \( \frac{y}{x} \). ### Conclusion: The final answer is that the ratio of the number of atoms of A to the number of atoms of B in the unit cell is \( y : x \). ---
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