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The atomic radius of strontium (Sr) is 2...

The atomic radius of strontium `(Sr)` is `215 p m` and it crystallizes with a cubic close packing . Edge length of the cube is `:`

A

4.30 pm

B

608.02 pm

C

496.53 pm

D

none of these

Text Solution

AI Generated Solution

The correct Answer is:
To find the edge length of the cube for strontium (Sr) which crystallizes in a cubic close packing (FCC), we can follow these steps: ### Step-by-Step Solution: 1. **Understand the Structure**: - Strontium crystallizes in a face-centered cubic (FCC) arrangement. In this arrangement, atoms are located at the corners and the centers of each face of the cube. 2. **Determine the Number of Atoms in FCC**: - In an FCC unit cell, there are 8 corner atoms, each contributing \( \frac{1}{8} \) of an atom to the unit cell, and 6 face-centered atoms, each contributing \( \frac{1}{2} \) of an atom. - Total contribution from corner atoms: \( 8 \times \frac{1}{8} = 1 \) - Total contribution from face-centered atoms: \( 6 \times \frac{1}{2} = 3 \) - Therefore, the total number of atoms (Z) in an FCC unit cell is \( 1 + 3 = 4 \). 3. **Relate Atomic Radius to Edge Length**: - The relationship between the atomic radius (R) and the edge length (a) of the cube in FCC is given by the formula: \[ a = 2\sqrt{2}R \] 4. **Substitute the Given Atomic Radius**: - The atomic radius of strontium (R) is given as \( 215 \, \text{pm} \). - Substitute R into the formula: \[ a = 2\sqrt{2} \times 215 \, \text{pm} \] 5. **Calculate the Edge Length**: - Calculate \( \sqrt{2} \): \[ \sqrt{2} \approx 1.414 \] - Now calculate \( a \): \[ a = 2 \times 1.414 \times 215 \, \text{pm} \] \[ a \approx 2 \times 1.414 \times 215 \approx 608.02 \, \text{pm} \] 6. **Final Result**: - The edge length of the cube is approximately \( 608.02 \, \text{pm} \). ### Final Answer: The edge length of the cube is \( 608.02 \, \text{pm} \). ---
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