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In the radius of the anion in an ionic a...

In the radius of the anion in an ionic acid solid is 200pm, what would be the radius of the cation that fits exactly into a cubic hole:

A

146.4pm

B

82.8pm

C

45pm

D

none of these

Text Solution

AI Generated Solution

The correct Answer is:
To find the radius of the cation that fits exactly into a cubic hole formed by an anion in an ionic solid, we can follow these steps: ### Step-by-Step Solution: 1. **Understand the Given Information**: - The radius of the anion (R⁻) is given as 200 picometers (pm). - We need to find the radius of the cation (R⁺) that fits into a cubic hole. 2. **Use the Radius Ratio for Cubic Holes**: - The radius ratio (R⁺/R⁻) for a cation fitting into a cubic hole is approximately 0.732. This means: \[ \frac{R^+}{R^-} = 0.732 \] 3. **Set Up the Equation**: - We can express the radius of the cation (R⁺) in terms of the radius of the anion (R⁻): \[ R^+ = 0.732 \times R^- \] 4. **Substitute the Value of R⁻**: - Substitute the given radius of the anion into the equation: \[ R^+ = 0.732 \times 200 \text{ pm} \] 5. **Calculate the Radius of the Cation**: - Performing the multiplication: \[ R^+ = 146.4 \text{ pm} \] 6. **Conclusion**: - The radius of the cation that fits exactly into the cubic hole is **146.4 picometers**. ### Final Answer: The radius of the cation is **146.4 pm**.
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