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In a solid, oxide ions are arrnged in cc...

In a solid, oxide ions are arrnged in ccp, cations A occupy A occupy `(1/8)^th` of the tetrahedral voids and cation B occupy `(1/4)^(th)` of the octahedral voids. The formula of the compound is:

A

`ABO_(4)`

B

`AB_(2)O_(3)`

C

`A_(@)BO_(4)`

D

`AB_(4)O_(4)`

Text Solution

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The correct Answer is:
To determine the formula of the compound formed by oxide ions, cation A, and cation B in a solid where oxide ions are arranged in cubic close packing (CCP), we can follow these steps: ### Step-by-Step Solution: 1. **Understanding the Arrangement**: - The oxide ions (O²⁻) are arranged in a cubic close packing (CCP) structure, which is also known as face-centered cubic (FCC). 2. **Calculating the Number of Oxide Ions**: - In a CCP structure, the number of ions per unit cell is 4 (1 from each of the 8 corners and 3 from the 6 face centers). - Therefore, the number of oxide ions (O²⁻) in the unit cell is 4. 3. **Identifying Tetrahedral and Octahedral Voids**: - The number of tetrahedral voids in a CCP structure is given by the formula: \[ \text{Number of Tetrahedral Voids} = 2 \times \text{Number of Atoms in CCP} = 2 \times 4 = 8 \] - The number of octahedral voids is equal to the number of atoms in the CCP structure, which is 4. 4. **Calculating Cations Occupying Voids**: - Cation A occupies \( \frac{1}{8} \) of the tetrahedral voids: \[ \text{Cation A} = \frac{1}{8} \times 8 = 1 \] - Cation B occupies \( \frac{1}{4} \) of the octahedral voids: \[ \text{Cation B} = \frac{1}{4} \times 4 = 1 \] 5. **Writing the Formula**: - Now we have: - Number of A cations = 1 - Number of B cations = 1 - Number of O²⁻ ions = 4 - Therefore, the formula of the compound can be written as: \[ \text{Formula} = A^1B^1O^{2-}_4 = ABO_4 \] ### Final Answer: The formula of the compound is **ABO₄**.
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