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Statement-1 C.N of Cs^(+) ion in CsCl st...

Statement-1 C.N of `Cs^(+)` ion in CsCl structure is 8
Statement -2 CsCl crystallizes in BCC structure

A

If both the statement are TRUE and STATEMENT -2 is the correct explanation of STATEMENT -1

B

If both the statement are TRUE and STATEMENT -2 is NOT the correct explanation of STATEMENT -1

C

If STATEMENT -1 is the correcct and TRUE and STATEMENT -2 is FALSE

D

If STATEMENT -1 is the correcct and FALSE and STATEMENT -2 is TRUE

Text Solution

AI Generated Solution

The correct Answer is:
To analyze the statements regarding the CsCl structure, we can break down the solution into clear steps: ### Step 1: Understand the CsCl Structure - CsCl (cesium chloride) crystallizes in a body-centered cubic (BCC) structure. In this structure, chloride ions (Cl⁻) occupy the corners of the cube, and cesium ions (Cs⁺) occupy the body center. ### Step 2: Identify the Coordination Number - The coordination number (C.N.) of an ion in a crystal structure is defined as the number of nearest neighboring ions surrounding it. - In the CsCl structure, the Cs⁺ ion is surrounded by 8 Cl⁻ ions located at the corners of the cube. Therefore, the coordination number of Cs⁺ is 8. ### Step 3: Verify the Statements - **Statement 1**: The coordination number of Cs⁺ in CsCl structure is 8. This statement is correct based on the arrangement of ions in the BCC structure. - **Statement 2**: CsCl crystallizes in a BCC structure. This statement is also correct as CsCl indeed adopts a BCC lattice. ### Step 4: Determine the Relationship Between the Statements - Since both statements are true, we need to assess if Statement 2 provides a correct explanation for Statement 1. The BCC structure directly leads to the coordination number of 8 for the Cs⁺ ion, as it is surrounded by 8 Cl⁻ ions. ### Conclusion - Both statements are true, and Statement 2 is the correct explanation for Statement 1. ### Final Answer - Both statements are true, and Statement 2 is the correct explanation for Statement 1. ---
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