Home
Class 11
CHEMISTRY
Find the distance ( in pm) between the b...

Find the distance ( in pm) between the body centered atoms and one corner atom in an element `( a = 2.32 "pm")`

Text Solution

AI Generated Solution

The correct Answer is:
To find the distance between the body-centered atom and one corner atom in a body-centered cubic (BCC) structure, we can follow these steps: ### Step 1: Understand the BCC Structure In a BCC structure, there are atoms located at the eight corners of the cube and one atom at the center of the cube. ### Step 2: Identify the Body Diagonal The distance we need to calculate is along the body diagonal of the cube. The body diagonal connects one corner atom to the body-centered atom. ### Step 3: Calculate the Length of the Body Diagonal The length of the body diagonal (d) of a cube with edge length \(a\) is given by the formula: \[ d = \sqrt{3} \times a \] ### Step 4: Relate the Body Diagonal to Atomic Radii In the BCC structure, along the body diagonal, the distance can also be expressed in terms of the atomic radii. The body diagonal consists of one corner atom, the body-centered atom, and another corner atom. The relationship can be expressed as: \[ d = r + 2r + r = 4r \] where \(r\) is the radius of the atom. ### Step 5: Set the Two Expressions Equal From the two expressions for the body diagonal, we have: \[ \sqrt{3} \times a = 4r \] ### Step 6: Solve for the Radius Rearranging the equation gives: \[ r = \frac{\sqrt{3} \times a}{4} \] ### Step 7: Substitute the Given Edge Length Now, substitute the given edge length \(a = 2.32 \, \text{pm}\): \[ r = \frac{\sqrt{3} \times 2.32}{4} \] ### Step 8: Calculate the Value of \(r\) Using \(\sqrt{3} \approx 1.732\): \[ r = \frac{1.732 \times 2.32}{4} \approx \frac{4.02304}{4} \approx 1.00576 \, \text{pm} \] ### Step 9: Calculate the Distance Between the Body Center Atom and One Corner Atom The distance between the body-centered atom and one corner atom is simply \(2r\): \[ \text{Distance} = 2r = 2 \times 1.00576 \approx 2.01152 \, \text{pm} \] ### Final Answer Thus, the distance between the body-centered atom and one corner atom is approximately: \[ \text{Distance} \approx 2.01 \, \text{pm} \]
Promotional Banner

Topper's Solved these Questions

  • SOLID STATE

    NARENDRA AWASTHI ENGLISH|Exercise Assertion - Reason type Question|11 Videos
  • IONIC EEQUILIBRIUM

    NARENDRA AWASTHI ENGLISH|Exercise Subjective problems|1 Videos
  • STOICHIOMETRY

    NARENDRA AWASTHI ENGLISH|Exercise Match the Colum-II|6 Videos

Similar Questions

Explore conceptually related problems

If a is the length of the side of a cube, the distance between the body centred atom and one corner atom in the cube will be:

If a is the length of the side of a cube, the distance between the body centred atom and one corner atom in the cube will be:

What is the relationship between the atomic mass and actual mass of one atom of an element ?

In a lattice of X and Y atoms, If X atoms are present at corners and Y atoms at the body centre & one X atom is removed from a corner from each unit cell, then the formula of the compound will be:

A cube-shaped crystal of an alkali metal, 1.62 mm on an edge, was vapourized in a 500.0 mL evacuated flask.The pressure of the resulting vapour was 12.5 mm of Hg at 802^@C .The structure of the solid metal is known to be body-centered cubic.What is the atomic radius of the metal atom in picometers ? (R=0.082 It-atm/mol-K) (The radii of metals atoms as Li=152 pm, Na=186 pm,K=227 pm,Rb=248 pm)

The internuclear distance between adjacent chlorine atoms of the two neighboring molecules in the soild state is 360 pm. Thus, the van der Waals radius of chlorine atom is_______.

In a f.c.c. arrangement of A and B atoms, where A atoms are at the corners of the unit cell and B atoms at the face - centres, one of the A atom is missing from one corner in each unit cell. The formula of compound is :

Consider a cube 1 of body-centered cubic unit cell of edge length 'a'. Now atom at the body center can be viewed to be lying on the corner of another cube 2. Find the volume common to cube 1 and cube 2.

Tungsten has a density of 19.35 g cm^(-3) and the length of the side of the unit cell is 316 pm. The unit cell is a body centred unit cell. How many atoms does 50 grams of the element contain?

The internuclear distance between two adjacent atoms of Ne is 360 pm . What will be its van der Waals radius ?