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Find the value of wave number (overset-v...

Find the value of wave number `(overset-v)` in terms of Rydberg's constant, when transition of electron takes place between two lvels of `He^(+)` ion whose sum is 4 and difference is 2.

A

`(8R)/(9)`

B

`(32R)/(9)`

C

`(3R)/(4)`

D

none of these

Text Solution

AI Generated Solution

The correct Answer is:
To find the value of the wave number \( \overset{v}{\text{}} \) in terms of Rydberg's constant for the transition of an electron in the \( \text{He}^+ \) ion, we can follow these steps: ### Step 1: Define the Energy Levels Let the two energy levels be \( n_1 \) and \( n_2 \). We are given two conditions: 1. The sum of the two levels: \[ n_1 + n_2 = 4 \] 2. The difference of the two levels: \[ n_1 - n_2 = 2 \] ### Step 2: Solve for \( n_1 \) and \( n_2 \) We can solve these two equations simultaneously. - Adding the two equations: \[ (n_1 + n_2) + (n_1 - n_2) = 4 + 2 \] This simplifies to: \[ 2n_1 = 6 \implies n_1 = 3 \] - Now, substituting \( n_1 = 3 \) back into the first equation: \[ 3 + n_2 = 4 \implies n_2 = 1 \] Thus, we have: \[ n_1 = 3, \quad n_2 = 1 \] ### Step 3: Calculate the Wave Number The wave number \( \overset{v}{\text{}} \) can be calculated using the formula: \[ \overset{v}{\text{}} = RZ^2 \left( \frac{1}{n_1^2} - \frac{1}{n_2^2} \right) \] where \( R \) is the Rydberg constant and \( Z \) is the atomic number. For \( \text{He}^+ \), \( Z = 2 \). Substituting the values: \[ \overset{v}{\text{}} = R(2^2) \left( \frac{1}{3^2} - \frac{1}{1^2} \right) \] \[ = R(4) \left( \frac{1}{9} - 1 \right) \] \[ = R(4) \left( \frac{1 - 9}{9} \right) \] \[ = R(4) \left( \frac{-8}{9} \right) \] \[ = -\frac{32R}{9} \] Since wave number is typically expressed as a positive quantity, we can write: \[ \overset{v}{\text{}} = \frac{32R}{9} \] ### Final Answer Thus, the value of the wave number in terms of Rydberg's constant is: \[ \overset{v}{\text{}} = \frac{32R}{9} \] ---
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