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Which electronic transition in a hydroge...

Which electronic transition in a hydrogen atom, starting from the orbit n=7, will produce infrared light of wavelength 2170 nm?
`(Given: R_(H)=1.09677xx10^(7)M^(-1))`

A

`n=7 " to " n=4`

B

from `n=2` to `n=4`

C

from `n=5` to `n=1`

D

from `n=3` to `n=5`

Text Solution

AI Generated Solution

The correct Answer is:
To determine which electronic transition in a hydrogen atom starting from the orbit \( n = 7 \) will produce infrared light of wavelength \( 2170 \, \text{nm} \), we can use the Rydberg formula for hydrogen: \[ \frac{1}{\lambda} = R_H \left( \frac{1}{n_1^2} - \frac{1}{n_2^2} \right) \] where: - \( \lambda \) is the wavelength of the emitted light, - \( R_H \) is the Rydberg constant for hydrogen, \( R_H = 1.09677 \times 10^7 \, \text{m}^{-1} \), - \( n_1 \) is the lower energy level, - \( n_2 \) is the higher energy level (in this case, \( n_2 = 7 \)). ### Step-by-step Solution: 1. **Convert Wavelength to Meters**: The given wavelength is \( 2170 \, \text{nm} \). We need to convert this to meters: \[ \lambda = 2170 \, \text{nm} = 2170 \times 10^{-9} \, \text{m} \] 2. **Substitute Values into the Rydberg Formula**: We know \( n_2 = 7 \) and \( R_H = 1.09677 \times 10^7 \, \text{m}^{-1} \). Substitute these values into the Rydberg formula: \[ \frac{1}{2170 \times 10^{-9}} = 1.09677 \times 10^7 \left( \frac{1}{n_1^2} - \frac{1}{7^2} \right) \] 3. **Calculate \( \frac{1}{\lambda} \)**: Calculate \( \frac{1}{2170 \times 10^{-9}} \): \[ \frac{1}{2170 \times 10^{-9}} \approx 4.608 \times 10^6 \, \text{m}^{-1} \] 4. **Set Up the Equation**: Now we can set up the equation: \[ 4.608 \times 10^6 = 1.09677 \times 10^7 \left( \frac{1}{n_1^2} - \frac{1}{49} \right) \] 5. **Isolate \( \frac{1}{n_1^2} \)**: Rearranging gives: \[ \frac{1}{n_1^2} - \frac{1}{49} = \frac{4.608 \times 10^6}{1.09677 \times 10^7} \] Calculate the right side: \[ \frac{4.608 \times 10^6}{1.09677 \times 10^7} \approx 0.420 \] Therefore: \[ \frac{1}{n_1^2} = 0.420 + \frac{1}{49} \] 6. **Calculate \( \frac{1}{49} \)**: \[ \frac{1}{49} \approx 0.0204 \] So: \[ \frac{1}{n_1^2} = 0.420 + 0.0204 \approx 0.4404 \] 7. **Find \( n_1^2 \)**: Taking the reciprocal: \[ n_1^2 \approx \frac{1}{0.4404} \approx 2.27 \] 8. **Calculate \( n_1 \)**: Taking the square root: \[ n_1 \approx \sqrt{2.27} \approx 1.5 \] Since \( n_1 \) must be an integer, we round it to \( n_1 = 4 \). 9. **Conclusion**: The electronic transition occurs from \( n_2 = 7 \) to \( n_1 = 4 \). ### Final Answer: The electronic transition in a hydrogen atom that produces infrared light of wavelength \( 2170 \, \text{nm} \) is from \( n = 7 \) to \( n = 4 \).
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