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An excited state of H atom emits a photo...

An excited state of H atom emits a photon of wavelength `lamda` and returns in the ground state. The principal quantum number of excited state is given by:

A

`sqrt(lamdaR(lamdaR-1))`

B

`sqrt((lamdaR)/((lamdaR-1))`

C

`sqrt(lamdaR(lamdaR-1)`

D

`sqrt((lamdaR-1)/((lamdaR))`

Text Solution

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The correct Answer is:
To find the principal quantum number of the excited state of a hydrogen atom that emits a photon of wavelength \( \lambda \) and returns to the ground state, we can follow these steps: ### Step-by-Step Solution 1. **Identify the Energy Levels**: - The ground state of hydrogen corresponds to the principal quantum number \( n_1 = 1 \). - The excited state corresponds to \( n_2 \), which we need to find. 2. **Use the Rydberg Formula**: - The Rydberg formula for the wavelengths of emitted photons is given by: \[ \frac{1}{\lambda} = R \cdot \left( \frac{1}{n_1^2} - \frac{1}{n_2^2} \right) \] - Here, \( R \) is the Rydberg constant, and for hydrogen, \( Z = 1 \). 3. **Substitute Known Values**: - Since \( n_1 = 1 \), we can substitute this into the formula: \[ \frac{1}{\lambda} = R \cdot \left( 1 - \frac{1}{n_2^2} \right) \] 4. **Rearrange the Equation**: - Rearranging the equation gives: \[ \frac{1}{\lambda} = R \cdot \left( 1 - \frac{1}{n_2^2} \right) \] - This can be rewritten as: \[ \frac{1}{\lambda} = R - \frac{R}{n_2^2} \] 5. **Isolate \( \frac{1}{n_2^2} \)**: - Rearranging further, we get: \[ \frac{R}{n_2^2} = R - \frac{1}{\lambda} \] - Thus, \[ \frac{1}{n_2^2} = \frac{R - \frac{1}{\lambda}}{R} \] 6. **Simplify the Expression**: - This leads to: \[ n_2^2 = \frac{R \cdot \lambda}{R \cdot \lambda - 1} \] 7. **Take the Square Root**: - Finally, taking the square root gives us the principal quantum number of the excited state: \[ n_2 = \sqrt{\frac{\lambda R}{\lambda R - 1}} \] ### Final Result The principal quantum number of the excited state \( n_2 \) is: \[ n_2 = \sqrt{\frac{\lambda R}{\lambda R - 1}} \]
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