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d^(6) configuration will result in tota...

`d^(6)` configuration will result in total spin of :

A

`3/2`

B

`1/2`

C

`2`

D

`1`

Text Solution

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The correct Answer is:
To determine the total spin for a \(d^6\) electron configuration, we can follow these steps: ### Step-by-Step Solution: 1. **Understand the Electron Configuration**: - The \(d\) subshell can hold a maximum of 10 electrons (5 orbitals, each can hold 2 electrons). - For \(d^6\), there are 6 electrons in the \(d\) orbitals. 2. **Apply Hund's Rule**: - According to Hund's rule, electrons will fill degenerate orbitals (orbitals of the same energy) singly before pairing up. - Therefore, the first 5 electrons will each occupy one of the 5 \(d\) orbitals singly. 3. **Distribute the Electrons**: - The first 5 electrons will occupy the 5 \(d\) orbitals with parallel spins (let's assume all are spin-up). - The 6th electron will pair up with one of the already occupied orbitals. 4. **Count the Spins**: - For the 5 electrons in the \(d\) orbitals, each contributes a spin of \(+\frac{1}{2}\). - The 6th electron, which is paired, will contribute a spin of \(-\frac{1}{2}\). 5. **Calculate the Total Spin**: - Total spin = (Number of spin-up electrons) \(\times \frac{1}{2} + (Number of spin-down electrons) \times (-\frac{1}{2})\) - Here, we have 5 spin-up electrons and 1 spin-down electron. - Total spin = \(5 \times \frac{1}{2} + 1 \times (-\frac{1}{2})\) - Total spin = \(\frac{5}{2} - \frac{1}{2} = \frac{4}{2} = 2\) 6. **Final Result**: - The total spin for the \(d^6\) configuration is **2**.
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