The quantum number of four electrons (el to e4) are given below :- `{:(,n,,l,,m,,s,,),(e1,3,,0,,0,,+1//2,,),(e2,4,,0,,0,,1//2,,),(e3,3,,2,,2,,-1//2,,),(e4,3,,1,,-1,,1//2,,):}` The correct order of decreasing energy of these electrons is :
A
`e4 gt e3 gt e2 gt e1`
B
`e2 gt e3 gt e4 gt e1`
C
`e3 gt e2 gt e4 gt e1`
D
`e1 gt e4 gt e2 gt e3`
Text Solution
AI Generated Solution
The correct Answer is:
To determine the correct order of decreasing energy of the electrons based on their quantum numbers, we will follow these steps:
### Step 1: Identify the Quantum Numbers
The quantum numbers for the electrons are:
- \( e_1: (n=3, l=0, m=0, s=+\frac{1}{2}) \)
- \( e_2: (n=4, l=0, m=0, s=+\frac{1}{2}) \)
- \( e_3: (n=3, l=2, m=2, s=-\frac{1}{2}) \)
- \( e_4: (n=3, l=1, m=-1, s=+\frac{1}{2}) \)
### Step 2: Calculate \( n + l \) Values
Next, we calculate the \( n + l \) values for each electron:
- For \( e_1 \): \( n + l = 3 + 0 = 3 \)
- For \( e_2 \): \( n + l = 4 + 0 = 4 \)
- For \( e_3 \): \( n + l = 3 + 2 = 5 \)
- For \( e_4 \): \( n + l = 3 + 1 = 4 \)
### Step 3: Determine Energy Order Based on \( n + l \)
The energy of an electron in an orbital is determined primarily by the \( n + l \) value:
- Higher \( n + l \) value means higher energy.
- If two orbitals have the same \( n + l \) value, the one with the higher \( n \) value has higher energy.
### Step 4: List \( n + l \) Values
Now we can list the \( n + l \) values:
- \( e_1: 3 \)
- \( e_2: 4 \)
- \( e_3: 5 \)
- \( e_4: 4 \)
### Step 5: Order by Energy
1. **Highest Energy**: \( e_3 \) (5)
2. **Next Highest**: \( e_2 \) (4) and \( e_4 \) (4) - compare \( n \) values:
- \( e_2 \) has \( n = 4 \) (higher)
- \( e_4 \) has \( n = 3 \) (lower)
3. **Lowest Energy**: \( e_1 \) (3)
### Final Order of Decreasing Energy
Thus, the order of decreasing energy is:
1. \( e_3 \)
2. \( e_2 \)
3. \( e_4 \)
4. \( e_1 \)
### Conclusion
The correct order of decreasing energy for the electrons is:
**\( e_3, e_2, e_4, e_1 \)**
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