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Which of the following electron configur...

Which of the following electron configurations is correct for copper,(atomic number29)

A

(a) [Ar]`3d^(10)4s^(1)`

B

(b) [Kr]`3d^(9)4s^(1)`

C

(c) [Ar]`3d^(9)4s^(2)`

D

(d) [Kr]`3d^(10)4s^(1)`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the correct electron configuration for copper (Cu), which has an atomic number of 29, we will follow these steps: ### Step 1: Determine the total number of electrons Since copper has an atomic number of 29, it has 29 electrons. ### Step 2: Write the expected electron configuration Following the Aufbau principle, we fill the orbitals in the order of increasing energy levels. The expected electron configuration for 29 electrons would be: - 1s² - 2s² - 2p⁶ - 3s² - 3p⁶ - 4s² - 3d⁹ So, the expected configuration is: \[ 1s^2 \, 2s^2 \, 2p^6 \, 3s^2 \, 3p^6 \, 4s^2 \, 3d^9 \] ### Step 3: Analyze the stability of the configuration However, this configuration is not the most stable for copper. The 3d subshell can hold a maximum of 10 electrons, and it is more stable when it is fully filled or half-filled. ### Step 4: Write the actual electron configuration To achieve greater stability, one electron from the 4s subshell is promoted to the 3d subshell. Therefore, the actual electron configuration for copper is: \[ 1s^2 \, 2s^2 \, 2p^6 \, 3s^2 \, 3p^6 \, 4s^1 \, 3d^{10} \] ### Step 5: Conclusion Thus, the correct electron configuration for copper is: \[ \text{Argon} \, 4s^1 \, 3d^{10} \]
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