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When an electron makes a transition from...

When an electron makes a transition from `(n+1)` state of nth state, the frequency of emitted radiations is related to n according to `(n gtgt 1)`:

A

(a) `v=(2cRZ^(2))/(n^(3))`

B

(b) `v=(cRZ^(2))/(n^(4))`

C

(c) `v=(cRZ^(2))/(n^(2))`

D

(d) `v=(2cRZ^(2))/(n^(2))`

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The correct Answer is:
To solve the problem of finding the relationship between the frequency of emitted radiation when an electron transitions from the (n+1) state to the nth state, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Transition**: The electron is transitioning from the (n+1) energy level to the nth energy level. This transition results in the emission of radiation. 2. **Use the Rydberg Formula**: The Rydberg formula for the wavelength (λ) of emitted radiation during such transitions is given by: \[ \frac{1}{\lambda} = RZ^2 \left( \frac{1}{n_1^2} - \frac{1}{n_2^2} \right) \] where \( R \) is the Rydberg constant, \( Z \) is the atomic number, \( n_1 \) is the lower energy level (n), and \( n_2 \) is the higher energy level (n+1). 3. **Substituting Values**: Substitute \( n_1 = n \) and \( n_2 = n + 1 \): \[ \frac{1}{\lambda} = RZ^2 \left( \frac{1}{n^2} - \frac{1}{(n+1)^2} \right) \] 4. **Simplify the Expression**: To simplify \( \frac{1}{n^2} - \frac{1}{(n+1)^2} \): \[ \frac{1}{n^2} - \frac{1}{(n+1)^2} = \frac{(n+1)^2 - n^2}{n^2(n+1)^2} = \frac{2n + 1}{n^2(n+1)^2} \] Thus, we have: \[ \frac{1}{\lambda} = RZ^2 \cdot \frac{2n + 1}{n^2(n+1)^2} \] 5. **Approximate for Large n**: Since \( n \) is much greater than 1, we can approximate \( (n+1)^2 \approx n^2 \): \[ \frac{1}{\lambda} \approx RZ^2 \cdot \frac{2n + 1}{n^4} \] Ignoring the 1 for large \( n \): \[ \frac{1}{\lambda} \approx \frac{2RZ^2}{n^3} \] 6. **Relate Wavelength to Frequency**: The relationship between frequency (ν) and wavelength (λ) is given by: \[ c = \nu \lambda \] Rearranging gives: \[ \nu = \frac{c}{\lambda} \] 7. **Substituting for λ**: Substitute \( \lambda \) from our previous step: \[ \nu = c \cdot \frac{1}{\frac{2RZ^2}{n^3}} = \frac{c n^3}{2RZ^2} \] 8. **Final Expression**: The frequency of the emitted radiation when an electron transitions from the (n+1) state to the nth state is: \[ \nu \propto \frac{1}{n^3} \] ### Conclusion: The frequency of emitted radiation is inversely proportional to the cube of the principal quantum number \( n \) when \( n \) is much greater than 1.
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