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Ozone in the upper atmoshphere absorbs u...

Ozone in the upper atmoshphere absorbs ultraviolet radiation which induces the following chemical reaction
`O_(3)(g)rightarrowO_(2)(g)+O(g)`
`O_(2)` produced in the above photochemical dissociation undergoes further dissociation into one normal oxygen atom (O) and more energetic oxygen atom `O**`.
`O_(2)(g) rightarrowO+O**`
`(O**)` has 1 eV more energy than(O) and normal dissociation energy of `O_(2)` is 480 kJ `"mol"^(-1)`.
[1 eV/Photon =96 kJ `"mol"^(-1)`]
If dissociation of `O_(3)` into `O_(2)` and O requires 400kJ `mol^(-1)` and O_(2) produced in this reaction is further dissociated to O and `O**` then the total energy required to for the dissociation of `O_(3)` into O and `O**` is :

A

1168kJ/mol

B

976kJ/mol

C

880kJ/mol

D

None of these

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to calculate the total energy required for the dissociation of ozone (O₃) into one normal oxygen atom (O) and one more energetic oxygen atom (O**). The process involves two steps, and we will break down the calculations step by step. ### Step 1: Energy for the dissociation of O₃ into O₂ and O The first reaction is: \[ O_3(g) \rightarrow O_2(g) + O(g) \] According to the problem, the energy required for this dissociation is given as: \[ \text{Energy required} = 400 \, \text{kJ/mol} \] ### Step 2: Energy for the dissociation of O₂ into O and O** The second reaction is: \[ O_2(g) \rightarrow O + O^* \] The normal dissociation energy of O₂ is given as: \[ \text{Normal dissociation energy} = 480 \, \text{kJ/mol} \] Additionally, O** has 1 eV more energy than O, which is equivalent to: \[ 1 \, \text{eV} = 96 \, \text{kJ/mol} \] Thus, the total energy required for the dissociation of O₂ into O and O** is: \[ \text{Total energy for O₂ dissociation} = 480 \, \text{kJ/mol} + 96 \, \text{kJ/mol} = 576 \, \text{kJ/mol} \] ### Step 3: Total energy for the dissociation of O₃ into O and O** Now, we combine the energies from Step 1 and Step 2 to find the total energy required for the dissociation of O₃ into O and O**: \[ \text{Total energy} = \text{Energy for O₃ dissociation} + \text{Energy for O₂ dissociation} \] \[ \text{Total energy} = 400 \, \text{kJ/mol} + 576 \, \text{kJ/mol} = 976 \, \text{kJ/mol} \] ### Final Answer The total energy required for the dissociation of O₃ into O and O** is: \[ \boxed{976 \, \text{kJ/mol}} \]
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