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The resistance of a conductivity cell co...

The resistance of a conductivity cell containing 0.001M KCl solution at 298K is 1500`Omega`. What is the cell constant ( in `mm^(-1)`) if the conductivity of 0.001M KCl solution is `2xx10^(-3)Smm^(-1)`

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To find the cell constant of a conductivity cell containing a 0.001 M KCl solution, we can follow these steps: ### Step 1: Understand the relationship between resistance, conductivity, and cell constant The relationship between resistance (R), conductivity (K), and the cell constant (L/A) can be expressed using the formula: \[ R = \frac{\rho L}{A} \] where: - \( R \) = resistance of the cell - \( \rho \) = resistivity of the solution - \( L \) = distance between the electrodes - \( A \) = surface area of the electrodes ### Step 2: Relate resistivity to conductivity Resistivity (\( \rho \)) is the reciprocal of conductivity (\( K \)): \[ \rho = \frac{1}{K} \] Substituting this into the resistance formula gives: \[ R = \frac{1}{K} \cdot \frac{L}{A} \] ### Step 3: Rearrange the formula to find the cell constant We can rearrange the formula to solve for the cell constant (\( \frac{L}{A} \)): \[ \frac{L}{A} = R \cdot K \] ### Step 4: Substitute the given values We are given: - Resistance (\( R \)) = 1500 Ω - Conductivity (\( K \)) = \( 2 \times 10^{-3} \, S \, mm^{-1} \) Now, substituting these values into the rearranged formula: \[ \frac{L}{A} = 1500 \, \Omega \cdot (2 \times 10^{-3} \, S \, mm^{-1}) \] ### Step 5: Calculate the cell constant Calculating the above expression: \[ \frac{L}{A} = 1500 \cdot 2 \times 10^{-3} \] \[ \frac{L}{A} = 3000 \times 10^{-3} \] \[ \frac{L}{A} = 3 \, mm^{-1} \] ### Final Answer The cell constant is \( 3 \, mm^{-1} \). ---
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