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Formation of a solution from two compone...

Formation of a solution from two components can be considered as :
(i) pure solvent `rarr` separated solvent molecules, `/_\H_(1)`
(ii) Pure solute `rarr`separated molecules,`/_\H_(2)`
(iii) separated solvent and solute molecules`rarr`solution, `/_\H_(3)`
solution so formed will be ideal if :

A

`/_\H_("soln")=/_\H_(1) + /_\H_(2) +/_\H_(3)`

B

`/_\H_("soln")=/_\H_(1) + /_\H_(2) -/_\H_(3)`

C

`/_\H_("soln")=/_\H_(1) -/_\H_(2) -/_\H_(3)`

D

`/_\H_("soln")=/_\H_(3) - /_\H_(1) -/_\H_(2)`

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To solve the problem regarding the formation of a solution from two components and determine the conditions for an ideal solution, we can break it down into the following steps: ### Step-by-Step Solution: 1. **Understanding the Components**: - We have two components: a solvent (A) and a solute (B). - The process of forming a solution can be divided into three steps: - (i) Converting pure solvent (A) into separated solvent molecules, which requires energy change denoted as ΔH1. - (ii) Converting pure solute (B) into separated solute molecules, which requires energy change denoted as ΔH2. - (iii) Mixing the separated solvent (A) and solute (B) molecules to form the solution, which has an energy change denoted as ΔH3. 2. **Energy Changes in Each Step**: - The energy required to separate the solvent molecules (ΔH1) and the energy required to separate the solute molecules (ΔH2) are both endothermic processes (they absorb energy). - The mixing of the separated solvent and solute molecules (ΔH3) can either be exothermic (releases energy) or endothermic (absorbs energy). 3. **Condition for Ideal Solutions**: - For a solution to be considered ideal, the overall enthalpy change (ΔH_solution) during the formation of the solution should be zero. - Mathematically, this can be expressed as: \[ ΔH_{solution} = ΔH_1 + ΔH_2 + ΔH_3 = 0 \] - Rearranging gives us: \[ ΔH_3 = - (ΔH_1 + ΔH_2) \] - This means that the energy released during the mixing (ΔH3) should exactly balance the energy absorbed during the separation of the solvent and solute. 4. **Conclusion**: - Therefore, the formation of an ideal solution occurs when the total enthalpy change (ΔH_solution) is zero, which implies that the interactions between the solute and solvent molecules (A-B interactions) are similar to those of the pure components (A-A and B-B interactions). ### Final Answer: The solution formed will be ideal if: \[ ΔH_{solution} = ΔH_1 + ΔH_2 + ΔH_3 = 0 \]
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