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Each question contains STATEMENT-I(Asser...

Each question contains STATEMENT-I(Assertion) and STATEMENT-2(Reason).the statement carefully and mark the correct answer according to the instruction given below:
STATEMENT - 1 : Elevation in boiling point will be high if the molal elevation constant of the liquid is high.
STATEMENT - 2 : Elevation in boiling point is a colligative property.

A

If both the statements are TRUE and STATEMENT-2 is the correct explanation STATEMENT-1

B

If both the statements are TRUE but STATEMENT-2 is NOT the correct explanation STATEMENT-1

C

If STATEMENT-1 is TRUE and STATEMENT-2 is FALSE

D

If STATEMENT-1 is FALSE and STATEMENT-2 is TRUE

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to analyze both statements provided: **STATEMENT - 1:** Elevation in boiling point will be high if the molal elevation constant of the liquid is high. **STATEMENT - 2:** Elevation in boiling point is a colligative property. ### Step-by-Step Solution: 1. **Understanding Elevation in Boiling Point:** - The elevation in boiling point (ΔTB) is a phenomenon where the boiling point of a solvent increases when a solute is dissolved in it. This can be mathematically expressed using the formula: \[ \Delta T_B = i \cdot K_B \cdot m \] - Here, \(i\) is the Van't Hoff factor (which represents the number of particles the solute breaks into), \(K_B\) is the molal elevation constant of the solvent, and \(m\) is the molality of the solution. 2. **Analyzing STATEMENT - 1:** - The first statement claims that if the molal elevation constant (\(K_B\)) is high, then the elevation in boiling point (\(ΔTB\)) will also be high. - From the formula, we can see that \(ΔTB\) is directly proportional to \(K_B\). Therefore, if \(K_B\) increases, \(ΔTB\) will also increase, making STATEMENT - 1 true. 3. **Analyzing STATEMENT - 2:** - The second statement states that elevation in boiling point is a colligative property. - Colligative properties depend on the number of solute particles in a solution, not on the nature of the solute. Since elevation in boiling point is indeed a colligative property, STATEMENT - 2 is also true. 4. **Determining the Relationship Between the Statements:** - While both statements are true, we need to determine if STATEMENT - 2 is the correct explanation for STATEMENT - 1. - STATEMENT - 1 is about the effect of the molal elevation constant on the boiling point elevation, while STATEMENT - 2 describes the nature of elevation in boiling point as a colligative property. They are related but do not explain each other directly. 5. **Conclusion:** - Since both statements are true but STATEMENT - 2 does not explain STATEMENT - 1, the correct answer is: - **If both the statements are true, but statement 2 is not the correct explanation of statement 1.** ### Final Answer: **Option B:** If both the statements are true, but statement 2 is not the correct explanation of statement 1.
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