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The strongest Bronsted base in the follo...

The strongest Bronsted base in the following anion is:

A

`CN^(-)`

B

`Cl^(-)`

C

`I^(-)`

D

`Br^(-)`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the strongest Bronsted base among the given anions, we need to follow these steps: ### Step 1: Understand Bronsted-Lowry Theory According to the Bronsted-Lowry theory, a Bronsted base is a species that can accept a proton (H⁺). When a base accepts a proton, it forms its conjugate acid. Conversely, an acid is a species that can donate a proton, forming its conjugate base. **Hint:** Remember that the strength of a base is inversely related to the strength of its conjugate acid. ### Step 2: Identify the Anions and Their Conjugate Acids We need to identify the anions given in the question and their corresponding conjugate acids. For example: - CN⁻ (cyanide ion) → HCN (hydrocyanic acid) - Cl⁻ (chloride ion) → HCl (hydrochloric acid) - I⁻ (iodide ion) → HI (hydroiodic acid) - Br⁻ (bromide ion) → HBr (hydrobromic acid) **Hint:** Write down the anions and their conjugate acids to visualize the relationship. ### Step 3: Determine the Strength of the Conjugate Acids Next, we need to evaluate the strength of the conjugate acids formed: - HCN: Weak acid - HCl: Strong acid - HI: Strong acid - HBr: Strong acid Among these, HCl is the weakest acid. **Hint:** Recall that strong acids have weak conjugate bases, while weak acids have strong conjugate bases. ### Step 4: Identify the Strongest Bronsted Base Since HCl is the weakest acid among the conjugate acids listed, its conjugate base (Cl⁻) will be the strongest Bronsted base. However, we are looking for the strongest Bronsted base among the anions provided. Since CN⁻ is the conjugate base of the weak acid HCN, it will be a stronger base than Cl⁻, I⁻, and Br⁻. **Hint:** The weaker the acid, the stronger its conjugate base. ### Conclusion Thus, among the given anions, CN⁻ (cyanide ion) is the strongest Bronsted base. **Final Answer:** The strongest Bronsted base is CN⁻.
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Knowledge Check

  • The strongest base is :

    A
    `CH_(3)-underset(underset(CH_(3))(|))(N)-CH_(3)`
    B
    C
    `C_(6)H_(5)-underset(underset(C_(6)H_(5))(|))(N)-C_(6)H_(5)`
    D
    `CH_(3)-NH-CH_(3)`
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