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0.01 M HA (aq.) is 2% dissociated, [OH^(...

`0.01` M HA (aq.) is `2%` dissociated, `[OH^(-)]` of solution is :

A

`2xx10^(-4)`

B

`10^(-8)`

C

`5xx10^(-11)`

D

`5xx10^(-12)`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to find the concentration of hydroxide ions \([OH^-]\) in a solution of 0.01 M HA that is 2% dissociated. Here’s a step-by-step solution: ### Step 1: Determine the concentration of \([H^+]\) Given that the acid HA is 2% dissociated, we can calculate the concentration of \([H^+]\) ions produced from the dissociation. 1. **Initial concentration of HA**: \[ C = 0.01 \, \text{M} \] 2. **Percentage dissociation**: \[ \text{Dissociation} = 2\% = \frac{2}{100} = 0.02 \] 3. **Concentration of \([H^+]\)**: \[ [H^+] = C \times \text{Dissociation} = 0.01 \times 0.02 = 0.0002 \, \text{M} = 2 \times 10^{-4} \, \text{M} \] ### Step 2: Use the ion product of water to find \([OH^-]\) The product of the concentrations of hydrogen ions and hydroxide ions in water at 25°C is given by: \[ K_w = [H^+][OH^-] = 10^{-14} \] 4. **Substituting the value of \([H^+]\)**: \[ [OH^-] = \frac{K_w}{[H^+]} = \frac{10^{-14}}{2 \times 10^{-4}} \] 5. **Calculating \([OH^-]\)**: \[ [OH^-] = \frac{10^{-14}}{2 \times 10^{-4}} = \frac{10^{-14}}{2} \times 10^{4} = 0.5 \times 10^{-10} \, \text{M} \] \[ [OH^-] = 5 \times 10^{-11} \, \text{M} \] ### Final Answer The concentration of hydroxide ions \([OH^-]\) in the solution is: \[ [OH^-] = 5 \times 10^{-11} \, \text{M} \] ---
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