Acid-base indicators are either weak organic acids or weak organic bases. Indicator change colour in dilute solution when the hydonium ion concentration reaches a particular calur For example. Phenolphthalein is a coloureless stbstance in any aqueous solution with a pH less than 8.3 In between the pH range 8.3 to 10, transition of colour (colourless to pink ) takes place and if pH of solution is greater than 10 solution is dark pink. Considering an acid indicator Hln, the equilibrium involving it and its conjgate base `In^(-)` can be represented as :
`" " underset("acidic from")(HIn)hArrH^(+)underset("basic from")(In^(-))`
pH of solution can be computed as :
`" " pH=pK_(In)+log.([IN^(-)])/([HIn])`
In general, transition of colour takes place in between the pH range `pK_(In+-1.`
Following is the titration curce of two acid HA and HB (5 milli-moles each) titrated against strong base NaOH(0.1M)
What is `pK_(a)` for HB acid ?

Options

A. 3
B. 4
C. 5
D. 6

Answer

C