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Which of the following expressions is tr...

Which of the following expressions is true for an ideal gas ?

A

`((delV)/(delT))_(P) = 0`

B

`((delP)/(delT))_(V) = 0`

C

`((delU)/(delP))_(T) = 0`

D

`((delU)/(delT))_(T) = 0`

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The correct Answer is:
To determine which expression is true for an ideal gas, we will analyze each option step by step using the ideal gas law and relevant thermodynamic equations. ### Step-by-Step Solution: 1. **Understanding the Ideal Gas Law**: The ideal gas law is given by the equation: \[ PV = nRT \] where \( P \) is pressure, \( V \) is volume, \( n \) is the number of moles, \( R \) is the universal gas constant, and \( T \) is temperature. 2. **Analyzing Option 1**: The first option states: \[ \frac{\Delta V}{\Delta T} \text{ at constant pressure} = 0 \] - From the ideal gas law, at constant pressure, we can differentiate: \[ P \frac{\Delta V}{\Delta T} = nR \] - This implies: \[ \frac{\Delta V}{\Delta T} = \frac{nR}{P} \] - Since \( nR/P \) is a constant (not zero), this option is **incorrect**. 3. **Analyzing Option 2**: The second option states: \[ \frac{\Delta P}{\Delta T} \text{ at constant volume} = 0 \] - Again, using the ideal gas law: \[ V \frac{\Delta P}{\Delta T} = nR \] - Thus: \[ \frac{\Delta P}{\Delta T} = \frac{nR}{V} \] - Since \( nR/V \) is also a constant (not zero), this option is **incorrect**. 4. **Analyzing Option 3**: The third option states: \[ \frac{\Delta U}{\Delta P} \text{ at constant temperature} = 0 \] - The change in internal energy \( \Delta U \) for an ideal gas is given by: \[ \Delta U = nC_v \Delta T \] - At constant temperature, \( \Delta T = 0 \), hence: \[ \Delta U = 0 \] - Therefore: \[ \frac{\Delta U}{\Delta P} = \frac{0}{\Delta P} = 0 \] - This option is **correct**. 5. **Analyzing Option 4**: The fourth option states: \[ \frac{\Delta U}{\Delta T} \text{ at constant temperature} = 0 \] - Here, we have: \[ \Delta U = nC_v \Delta T \] - Thus: \[ \frac{\Delta U}{\Delta T} = nC_v \] - Since \( nC_v \) is not zero, this option is **incorrect**. ### Conclusion: The correct answer is **Option 3**: \(\frac{\Delta U}{\Delta P} \text{ at constant temperature} = 0\).

To determine which expression is true for an ideal gas, we will analyze each option step by step using the ideal gas law and relevant thermodynamic equations. ### Step-by-Step Solution: 1. **Understanding the Ideal Gas Law**: The ideal gas law is given by the equation: \[ PV = nRT ...
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NARENDRA AWASTHI ENGLISH-THERMODYNAMICS-Level 3
  1. Which of the following expressions is true for an ideal gas ?

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  2. The first law of thermodynamics for a closed system is dU = dq + dw, w...

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  3. The first law of thermodynamics for a closed system is dU = dq + dw, w...

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  4. If the boundary of system moves by an infinitesimal amount, the work i...

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  5. If the boundary of system moves by an infinitesimal amount, the work i...

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  6. If the boundary of system moves by an infinitesimal amount, the work i...

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  7. If the boundary of system moves by an infinitesimal amount, the work i...

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  8. Standard Gibb's energy of reaction (Delta(r )G^(@)) at a certain temp...

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  9. Standard Gibb's energy of reaction (Delta(r )G^(@)) at a certain temp...

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  10. Standard Gibb's energy of reaction (Delta(r )G^(@)) at a certain temp...

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  11. Standard Gibb's energy of reaction (Delta(r )G^(@)) at a certain temp...

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  12. Consider the following reaction : CO(g)+2H(2)(g)iffCH(3)OH(g) Give...

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  13. Enthalpy of neutralization is defined as the enthalpy change when 1 mo...

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  14. Enthalpy of neutralzation is defined as the enthalpy change when 1 mol...

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  15. Enthalpy of neutralzation is defined as the enthalpy change when 1 mol...

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  16. Gibbs Helmholtz equation relates the enthalpy, entropy and free energy...

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  17. Gibbs Helmholtz equation relates the enthalpy, entropy and free energy...

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  18. Gibbs Helmholtz equation relates the enthalpy, entropy and free energy...

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  19. Identify the intensive quantities from the following : (a)Enthalpy ...

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  20. Identify the extensive quantities from the following :

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  21. Identify the state functions from the following :

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