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Which of the following option is correct...

Which of the following option is correct ?

A

`[(del lnK_(p))/(delT)]=(DeltaH^(@))/(RT^(2))`

B

`(dellnK)/(delT)=(E_(a))/(RT^(2))`

C

`[(dellnK_(p))/(delT)]=(DeltaU)/(RT^(2))`

D

All of these

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AI Generated Solution

The correct Answer is:
To determine the correct option from the given statements, we will analyze each statement step by step. ### Step-by-Step Solution: 1. **Understanding the First Statement:** - The first statement is: \[ \frac{\partial \ln K_p}{\partial T} = \frac{\Delta H^0}{RT^2} \] - This equation is known as the Clausius-Clapeyron equation, which relates the change in the natural logarithm of the equilibrium constant \( K_p \) to temperature \( T \) and the standard enthalpy change \( \Delta H^0 \). - **Conclusion:** This statement is correct. 2. **Understanding the Second Statement:** - The second statement is: \[ \frac{\partial \ln K}{\partial T} = \frac{E_A}{RT^2} \] - This equation is derived from the Arrhenius equation, which describes the temperature dependence of reaction rates. Here, \( E_A \) is the activation energy. - By taking the natural logarithm of the Arrhenius equation and differentiating with respect to temperature, we arrive at this relation. - **Conclusion:** This statement is also correct. 3. **Understanding the Third Statement:** - The third statement is: \[ \frac{\partial \ln K_p}{\partial T} = \frac{\Delta U}{RT^2} \] - This statement is incorrect. The correct relation involves the enthalpy change \( \Delta H^0 \), not the internal energy change \( \Delta U \). - If we express \( \Delta H^0 \) in terms of \( \Delta U \) and the work done (using the relation \( \Delta H = \Delta U + P \Delta V \)), we find that this does not simplify to the given statement. - **Conclusion:** This statement is incorrect. ### Final Conclusion: - The correct options are **A** and **B**. - The incorrect option is **C**.

To determine the correct option from the given statements, we will analyze each statement step by step. ### Step-by-Step Solution: 1. **Understanding the First Statement:** - The first statement is: \[ \frac{\partial \ln K_p}{\partial T} = \frac{\Delta H^0}{RT^2} ...
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NARENDRA AWASTHI ENGLISH-THERMODYNAMICS-Level 3
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  11. Standard Gibb's energy of reaction (Delta(r )G^(@)) at a certain temp...

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  15. Enthalpy of neutralzation is defined as the enthalpy change when 1 mol...

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  16. Gibbs Helmholtz equation relates the enthalpy, entropy and free energy...

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  17. Gibbs Helmholtz equation relates the enthalpy, entropy and free energy...

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  18. Gibbs Helmholtz equation relates the enthalpy, entropy and free energy...

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