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An imaginary reaction X rarr Y takes pla...

An imaginary reaction `X rarr Y` takes place in three steps
`X rarr A, DeltaH=-q_(1), " "BrarrA, DeltaH=-q_(2), " "BrarrY, DeltaH=-q_(3)`
If Hess's law is applicable, then the heat of the reaction `(X rarr Y)` is :

A

`q_(1)-q_(2)+q_(3)`

B

`q_(2)-q_(3)-q_(1)`

C

`q_(1)-q_(2)-q_(3)`

D

`q_(3)-q_(2)-q_(1)`

Text Solution

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The correct Answer is:
To solve the problem, we will apply Hess's law, which states that the total enthalpy change for a reaction is equal to the sum of the enthalpy changes for the individual steps that lead to that reaction. ### Step-by-Step Solution: 1. **Identify the Steps of the Reaction:** The reaction occurs in three steps: - Step 1: \( X \rightarrow A \) with \( \Delta H = -q_1 \) - Step 2: \( A \rightarrow B \) with \( \Delta H = -q_2 \) - Step 3: \( B \rightarrow Y \) with \( \Delta H = -q_3 \) 2. **Write the Enthalpy Changes:** From the steps, we can write the enthalpy changes: - For Step 1: \( \Delta H_1 = -q_1 \) - For Step 2: \( \Delta H_2 = -q_2 \) - For Step 3: \( \Delta H_3 = -q_3 \) 3. **Apply Hess's Law:** According to Hess's law, the total enthalpy change for the overall reaction \( X \rightarrow Y \) is the sum of the enthalpy changes of the individual steps: \[ \Delta H_{total} = \Delta H_1 + \Delta H_2 + \Delta H_3 \] 4. **Substitute the Enthalpy Changes:** Substituting the values from the steps: \[ \Delta H_{total} = (-q_1) + (-q_2) + (-q_3) \] This simplifies to: \[ \Delta H_{total} = -q_1 - q_2 - q_3 \] 5. **Rearranging the Equation:** To express the heat of the reaction \( X \rightarrow Y \) in a more useful form, we can rearrange the equation: \[ \Delta H_{total} = -(q_1 + q_2 + q_3) \] However, if we want to express it in terms of absorbed and released heat, we can consider the heat absorbed in the reverse direction. 6. **Final Expression:** The heat of the reaction \( X \rightarrow Y \) can be expressed as: \[ \Delta H_{reaction} = q_2 - q_1 - q_3 \] Thus, the heat of the reaction \( X \rightarrow Y \) is: \[ \Delta H_{reaction} = q_2 - q_1 - q_3 \] ### Conclusion: The heat of the reaction \( X \rightarrow Y \) is given by: \[ \Delta H_{reaction} = q_2 - q_1 - q_3 \]

To solve the problem, we will apply Hess's law, which states that the total enthalpy change for a reaction is equal to the sum of the enthalpy changes for the individual steps that lead to that reaction. ### Step-by-Step Solution: 1. **Identify the Steps of the Reaction:** The reaction occurs in three steps: - Step 1: \( X \rightarrow A \) with \( \Delta H = -q_1 \) - Step 2: \( A \rightarrow B \) with \( \Delta H = -q_2 \) ...
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