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Which of the following is/are correct?...

Which of the following is/are correct?

A

`DeltaH=DeltaU+Delta(PV)` when P and V both changes

B

`DeltaH=DeltaU+PDeltaV` when pressure is constant

C

`DeltaH=DeltaU+VDeltaP` when volume is constant

D

`DeltaH=DeltaU+PDeltaV+VDeltaP` when P and V both changes

Text Solution

AI Generated Solution

The correct Answer is:
To determine which of the statements regarding thermodynamics are correct, we will analyze the relationships between enthalpy (ΔH), internal energy (ΔU), pressure (P), and volume (V). ### Step-by-Step Solution: 1. **Understanding the Relationship Between ΔH and ΔU**: The first relationship we need to consider is: \[ \Delta H = \Delta U + \Delta (PV) \] This equation is valid when both pressure (P) and volume (V) change during a process. 2. **Constant Pressure Scenario**: If the pressure (P) is constant, we can simplify the equation: \[ \Delta U = \Delta H - P \Delta V \] Here, since P is constant, we can factor it out, leading to: \[ \Delta U = P \Delta V \] This shows that the change in internal energy (ΔU) is directly related to the work done by the system at constant pressure. 3. **Constant Volume Scenario**: If the volume (V) is constant, the change in entropy (ds) can be expressed as: \[ ds = V dP \] In this case, since V is constant, it can be factored out of the differential, indicating that the change in entropy is dependent on the change in pressure. 4. **General Case for Δ(PV)**: When both pressure and volume change, the change in the product PV can be expressed as: \[ \Delta(PV) = P \Delta V + V \Delta P \] This equation shows how the changes in both pressure and volume contribute to the overall change in the product PV. 5. **Conclusion**: All the relationships derived above are correct under their respective conditions. Therefore, the conclusion is that all the statements provided in the question are correct. ### Summary of Correct Statements: - ΔH = ΔU + Δ(PV) when both P and V change. - ΔU = PΔV when P is constant. - ds = VdP when V is constant. - Δ(PV) = PΔV + VΔP when both P and V change.

To determine which of the statements regarding thermodynamics are correct, we will analyze the relationships between enthalpy (ΔH), internal energy (ΔU), pressure (P), and volume (V). ### Step-by-Step Solution: 1. **Understanding the Relationship Between ΔH and ΔU**: The first relationship we need to consider is: \[ \Delta H = \Delta U + \Delta (PV) ...
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