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A 0.50 L container is ocupied by nitroge...

A 0.50 L container is ocupied by nitrogen at a pressure of 800 torr and a temperature of `0^(@)C`. The container can only withstand a pressure of 3.0 atm. What is the highest temperature `("^(@)C)` to which the container may be heated?

A

505

B

450

C

625

D

560

Text Solution

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The correct Answer is:
To solve the problem, we will use the relationship between pressure and temperature for a gas at constant volume, which can be derived from the ideal gas law. Here's a step-by-step solution: ### Step 1: Identify the given values - Volume (V) = 0.50 L (not needed for calculations since it's constant) - Initial Pressure (P1) = 800 torr - Maximum Pressure (P2) = 3.0 atm - Initial Temperature (T1) = 0°C = 273 K (convert to Kelvin) ### Step 2: Convert P1 from torr to atm To convert the pressure from torr to atm, we use the conversion factor: 1 atm = 760 torr \[ P1 = \frac{800 \text{ torr}}{760 \text{ torr/atm}} \approx 1.05 \text{ atm} \] ### Step 3: Use the relationship between pressure and temperature Since the volume and the number of moles of gas are constant, we can use the formula that relates pressure and temperature: \[ \frac{P1}{P2} = \frac{T1}{T2} \] Where: - \(P1\) = initial pressure - \(P2\) = maximum pressure - \(T1\) = initial temperature in Kelvin - \(T2\) = final temperature in Kelvin (which we want to find) ### Step 4: Substitute the known values into the equation Substituting the known values into the equation: \[ \frac{1.05 \text{ atm}}{3.0 \text{ atm}} = \frac{273 \text{ K}}{T2} \] ### Step 5: Solve for T2 Cross-multiplying to solve for \(T2\): \[ 1.05 \times T2 = 3.0 \times 273 \] Calculating the right side: \[ 1.05 \times T2 = 819 \] Now, divide both sides by 1.05: \[ T2 = \frac{819}{1.05} \approx 780 \text{ K} \] ### Step 6: Convert T2 from Kelvin to Celsius To convert from Kelvin to Celsius: \[ T2 = 780 \text{ K} - 273 = 507 \text{ °C} \] ### Final Answer The highest temperature to which the container may be heated is approximately **507 °C**. ---

To solve the problem, we will use the relationship between pressure and temperature for a gas at constant volume, which can be derived from the ideal gas law. Here's a step-by-step solution: ### Step 1: Identify the given values - Volume (V) = 0.50 L (not needed for calculations since it's constant) - Initial Pressure (P1) = 800 torr - Maximum Pressure (P2) = 3.0 atm - Initial Temperature (T1) = 0°C = 273 K (convert to Kelvin) ...
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