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If T(1),T(2) and T(3) are the temperatur...

If `T_(1),T_(2)` and `T_(3)` are the temperatures at which the `u_("rms"),u_("average"),u_("mp")` of oxygen gas are all equal to 1500 m/s then the correct statement is :

A

`T_(1)gtT_(2)gtT_(3)`

B

`T_(1)ltT_(2)ltT_(3)`

C

`T_(1)=T_(2)=T_(3)`

D

None of these

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to find the temperatures \( T_1, T_2, \) and \( T_3 \) at which the root mean square speed (\( u_{rms} \)), average speed (\( u_{average} \)), and most probable speed (\( u_{mp} \)) of oxygen gas are all equal to 1500 m/s. We will use the formulas for each of these speeds and derive the corresponding temperatures. ### Step 1: Write the formula for \( u_{rms} \) The formula for the root mean square speed (\( u_{rms} \)) is given by: \[ u_{rms} = \sqrt{\frac{3RT}{M}} \] Where: - \( R \) is the universal gas constant, - \( T \) is the temperature in Kelvin, - \( M \) is the molar mass of the gas. Given that \( u_{rms} = 1500 \, \text{m/s} \), we can set up the equation: \[ \sqrt{\frac{3RT_1}{M}} = 1500 \] ### Step 2: Solve for \( T_1 \) Squaring both sides gives: \[ \frac{3RT_1}{M} = 1500^2 \] Rearranging for \( T_1 \): \[ T_1 = \frac{1500^2 \cdot M}{3R} \] Calculating \( T_1 \): Assuming \( R \) and \( M \) are constants, we can compute \( T_1 \) numerically. Let's say \( R = 8.314 \, \text{J/(mol·K)} \) and \( M \) for oxygen is approximately \( 32 \, \text{g/mol} = 0.032 \, \text{kg/mol} \): \[ T_1 = \frac{1500^2 \cdot 0.032}{3 \cdot 8.314} \] Calculating this gives: \[ T_1 \approx 750000 \, \text{K} \] ### Step 3: Write the formula for \( u_{average} \) The formula for the average speed (\( u_{average} \)) is given by: \[ u_{average} = \sqrt{\frac{8RT}{\pi M}} \] Setting \( u_{average} = 1500 \, \text{m/s} \): \[ \sqrt{\frac{8RT_2}{\pi M}} = 1500 \] ### Step 4: Solve for \( T_2 \) Squaring both sides gives: \[ \frac{8RT_2}{\pi M} = 1500^2 \] Rearranging for \( T_2 \): \[ T_2 = \frac{1500^2 \cdot \pi M}{8R} \] Calculating \( T_2 \): Using the same values for \( R \) and \( M \): \[ T_2 = \frac{1500^2 \cdot \pi \cdot 0.032}{8 \cdot 8.314} \] Calculating this gives: \[ T_2 \approx 883125 \, \text{K} \] ### Step 5: Write the formula for \( u_{mp} \) The formula for the most probable speed (\( u_{mp} \)) is given by: \[ u_{mp} = \sqrt{\frac{2RT}{M}} \] Setting \( u_{mp} = 1500 \, \text{m/s} \): \[ \sqrt{\frac{2RT_3}{M}} = 1500 \] ### Step 6: Solve for \( T_3 \) Squaring both sides gives: \[ \frac{2RT_3}{M} = 1500^2 \] Rearranging for \( T_3 \): \[ T_3 = \frac{1500^2 \cdot M}{2R} \] Calculating \( T_3 \): Using the same values for \( R \) and \( M \): \[ T_3 = \frac{1500^2 \cdot 0.032}{2 \cdot 8.314} \] Calculating this gives: \[ T_3 \approx 1125000 \, \text{K} \] ### Step 7: Compare the temperatures Now we have: - \( T_1 \approx 750000 \, \text{K} \) - \( T_2 \approx 883125 \, \text{K} \) - \( T_3 \approx 1125000 \, \text{K} \) From this, we can conclude: \[ T_1 < T_2 < T_3 \] ### Final Answer The correct statement is \( T_1 < T_2 < T_3 \).

To solve the problem, we need to find the temperatures \( T_1, T_2, \) and \( T_3 \) at which the root mean square speed (\( u_{rms} \)), average speed (\( u_{average} \)), and most probable speed (\( u_{mp} \)) of oxygen gas are all equal to 1500 m/s. We will use the formulas for each of these speeds and derive the corresponding temperatures. ### Step 1: Write the formula for \( u_{rms} \) The formula for the root mean square speed (\( u_{rms} \)) is given by: \[ u_{rms} = \sqrt{\frac{3RT}{M}} ...
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