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Select the incorrect statement(s) :...

Select the incorrect statement(s) :

A

The product of pressure and volume of fixed amount of a gas is independent of temperature.

B

The value of universal gas constant depends upon temperature, volume and number of gaseous molecules

C

The gas constant also known as Boltzmann's constant

D

The average kinetic energy of molecules depends only on temperature

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question of identifying the incorrect statements regarding the gaseous state, we will analyze each statement one by one. ### Step 1: Analyze Statement 1 **Statement 1:** The product of pressure and volume of a fixed amount of gas is independent of temperature. - According to the Ideal Gas Law, \( PV = nRT \), where \( P \) is pressure, \( V \) is volume, \( n \) is the number of moles, \( R \) is the universal gas constant, and \( T \) is temperature. - For a fixed amount of gas (constant \( n \)), the product \( PV \) is directly proportional to \( T \). - Therefore, this statement is incorrect because \( PV \) is dependent on temperature. ### Step 2: Analyze Statement 2 **Statement 2:** The value of the universal gas constant depends upon temperature, volume, and number of gaseous molecules. - The universal gas constant \( R \) is a constant value that does not change with temperature, volume, or the number of molecules. - It is a fixed value used in the Ideal Gas Law. - Thus, this statement is also incorrect. ### Step 3: Analyze Statement 3 **Statement 3:** The gas constant is also known as the Boltzmann constant. - The gas constant \( R \) is related to the Boltzmann constant \( k \) by the equation \( R = k \cdot N_A \), where \( N_A \) is Avogadro's number. - Therefore, \( R \) is not the same as \( k \), making this statement incorrect. ### Step 4: Analyze Statement 4 **Statement 4:** The average kinetic energy of a molecule depends only on temperature. - The average kinetic energy of gas molecules can be expressed as \( KE = \frac{3}{2} k T \) or \( KE = \frac{3}{2} R T \) for one mole of gas. - In both expressions, the average kinetic energy is directly proportional to temperature \( T \) and does not depend on other factors. - Therefore, this statement is correct. ### Conclusion The incorrect statements are: - Statement 1 - Statement 2 - Statement 3 ### Final Answer The answer to the question is that statements 1, 2, and 3 are incorrect. ---

To solve the question of identifying the incorrect statements regarding the gaseous state, we will analyze each statement one by one. ### Step 1: Analyze Statement 1 **Statement 1:** The product of pressure and volume of a fixed amount of gas is independent of temperature. - According to the Ideal Gas Law, \( PV = nRT \), where \( P \) is pressure, \( V \) is volume, \( n \) is the number of moles, \( R \) is the universal gas constant, and \( T \) is temperature. - For a fixed amount of gas (constant \( n \)), the product \( PV \) is directly proportional to \( T \). - Therefore, this statement is incorrect because \( PV \) is dependent on temperature. ...
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