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Assertion: Helium shows only positive de...

Assertion: Helium shows only positive deviations from ideal behaviour.
Reason: Helium is an inert gas.

A

If both the statement are TRUE and STATEMENT-2 is the correct explanation of STATEMENT-1

B

If both the statement are TRUE but STATEMENT-2 is NOT the correct explanation of STATEMENT-1

C

If STATEMENT-1 is TRUE and STATEMENT-2 is FALSE

D

If STATEMENT-1 is FALSE and STATEMENT-2 is TRUE

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the assertion and reason about helium's behavior as a gas, we will break down the concepts step by step. ### Step 1: Understanding the Assertion The assertion states that "Helium shows only positive deviations from ideal behavior." **Explanation**: - An ideal gas follows the ideal gas law, represented by the equation \( PV = nRT \). - Real gases deviate from this behavior due to intermolecular forces and the volume occupied by gas particles. - Positive deviation occurs when the pressure of a real gas is greater than what is predicted by the ideal gas law, indicating weaker intermolecular forces. ### Step 2: Understanding the Reason The reason states that "Helium is an inert gas." **Explanation**: - Helium is classified as an inert gas (noble gas) because it has a complete outer electron shell (1s² configuration), which makes it chemically nonreactive under standard conditions. - While being an inert gas contributes to its behavior, it does not directly explain why it shows only positive deviations from ideal gas behavior. ### Step 3: Analyzing the Relationship Now we need to analyze the relationship between the assertion and the reason. **Explanation**: - Both statements are true: helium does show positive deviations from ideal gas behavior, and it is indeed an inert gas. - However, the reason does not explain the assertion. The positive deviation is primarily due to the weak intermolecular forces in helium, not its inert nature. ### Step 4: Conclusion Based on the analysis, we conclude that: - The assertion is true. - The reason is true. - The reason does not correctly explain the assertion. Thus, the correct answer is that both statements are true, but the second statement is not a correct explanation of the first. ### Final Answer: Both statements are true, but statement 2 is not a correct explanation of statement 1. ---
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