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He is kept in a rigid container of volum...

He is kept in a rigid container of volume `67.2` ltr at `STP`. The heat supplied to the gas to increases its temperature by `20^(@)C` is :

A

`780J`

B

`748J`

C

`718J`

D

`680J`

Text Solution

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The correct Answer is:
To solve the problem of calculating the heat supplied to a rigid container of helium gas to increase its temperature by \(20^\circ C\), we can follow these steps: ### Step 1: Understand the formula for heat supplied The heat supplied to a gas at constant volume can be calculated using the formula: \[ Q = N C_V \Delta T \] where: - \(Q\) is the heat supplied, - \(N\) is the number of moles of the gas, - \(C_V\) is the specific heat at constant volume, - \(\Delta T\) is the change in temperature. ### Step 2: Calculate the number of moles \(N\) To find the number of moles \(N\), we use the ideal gas law. At standard temperature and pressure (STP), 1 mole of an ideal gas occupies 22.4 liters. Therefore, the number of moles can be calculated as: \[ N = \frac{\text{Volume of gas}}{\text{Volume per mole at STP}} = \frac{67.2 \, \text{liters}}{22.4 \, \text{liters/mole}} = 3 \, \text{moles} \] ### Step 3: Determine the specific heat at constant volume \(C_V\) For a monoatomic ideal gas like helium, the specific heat at constant volume is given by: \[ C_V = \frac{3}{2} R \] where \(R\) is the universal gas constant, approximately \(8.314 \, \text{J/(mol K)}\). Thus, \[ C_V = \frac{3}{2} \times 8.314 \, \text{J/(mol K)} = 12.471 \, \text{J/(mol K)} \] ### Step 4: Calculate the change in temperature \(\Delta T\) The change in temperature is given as: \[ \Delta T = 20^\circ C \] Note that the change in temperature in Celsius is equivalent to the change in Kelvin. ### Step 5: Substitute values into the heat equation Now, we can substitute the values into the heat equation: \[ Q = N C_V \Delta T = 3 \, \text{moles} \times 12.471 \, \text{J/(mol K)} \times 20 \, \text{K} \] ### Step 6: Perform the calculation Calculating \(Q\): \[ Q = 3 \times 12.471 \times 20 = 748.26 \, \text{J} \] We can round this to: \[ Q \approx 748 \, \text{J} \] ### Final Answer The heat supplied to the gas to increase its temperature by \(20^\circ C\) is approximately **748 Joules**. ---
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