Given that `E_(O_(2))^(ɵ)//H_(2)O=+1.23V`, `E_(S_(2)O_(8)^(2-)//SO_(4)^(-2))=2.05V` `E_(Br_(2)^(ɵ)//Br-=+1.09V`, `E_(Au^(ɵ)^(3+)//Au=+1.4V` The strongest oxidizing agent is :
A
`Au^(3+)`
B
`O_(2)`
C
`S_(2)O_(8)^(2-)`
D
`Br_(2)`
Text Solution
AI Generated Solution
The correct Answer is:
To determine the strongest oxidizing agent from the given standard reduction potentials, we will follow these steps:
### Step 1: Understand the concept of oxidizing agents
An oxidizing agent is a substance that gains electrons in a chemical reaction and is reduced. The strength of an oxidizing agent is indicated by its standard reduction potential (E°). The higher the E° value, the stronger the oxidizing agent.
### Step 2: List the given standard reduction potentials
We have the following standard reduction potentials:
1. \( E^{\circ}_{O_2/H_2O} = +1.23 \, V \)
2. \( E^{\circ}_{S_2O_8^{2-}/SO_4^{2-}} = +2.05 \, V \)
3. \( E^{\circ}_{Br_2/Br^-} = +1.09 \, V \)
4. \( E^{\circ}_{Au^{3+}/Au} = +1.40 \, V \)
### Step 3: Compare the standard reduction potentials
Now we will compare the values of the standard reduction potentials:
- \( E^{\circ}_{O_2/H_2O} = +1.23 \, V \)
- \( E^{\circ}_{S_2O_8^{2-}/SO_4^{2-}} = +2.05 \, V \)
- \( E^{\circ}_{Br_2/Br^-} = +1.09 \, V \)
- \( E^{\circ}_{Au^{3+}/Au} = +1.40 \, V \)
### Step 4: Identify the highest value
From the comparison:
- The highest standard reduction potential is \( +2.05 \, V \) for \( S_2O_8^{2-}/SO_4^{2-} \).
### Step 5: Conclusion
Since \( S_2O_8^{2-} \) has the highest standard reduction potential, it is the strongest oxidizing agent among the given options.
### Final Answer
The strongest oxidizing agent is \( S_2O_8^{2-} \).
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