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Given that E(O(2))^(ɵ)//H(2)O=+1.23V, ...

Given that `E_(O_(2))^(ɵ)//H_(2)O=+1.23V`,
`E_(S_(2)O_(8)^(2-)//SO_(4)^(-2))=2.05V`
`E_(Br_(2)^(ɵ)//Br-=+1.09V`,
`E_(Au^(ɵ)^(3+)//Au=+1.4V`
The strongest oxidizing agent is :

A

`Au^(3+)`

B

`O_(2)`

C

`S_(2)O_(8)^(2-)`

D

`Br_(2)`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the strongest oxidizing agent from the given standard reduction potentials, we will follow these steps: ### Step 1: Understand the concept of oxidizing agents An oxidizing agent is a substance that gains electrons in a chemical reaction and is reduced. The strength of an oxidizing agent is indicated by its standard reduction potential (E°). The higher the E° value, the stronger the oxidizing agent. ### Step 2: List the given standard reduction potentials We have the following standard reduction potentials: 1. \( E^{\circ}_{O_2/H_2O} = +1.23 \, V \) 2. \( E^{\circ}_{S_2O_8^{2-}/SO_4^{2-}} = +2.05 \, V \) 3. \( E^{\circ}_{Br_2/Br^-} = +1.09 \, V \) 4. \( E^{\circ}_{Au^{3+}/Au} = +1.40 \, V \) ### Step 3: Compare the standard reduction potentials Now we will compare the values of the standard reduction potentials: - \( E^{\circ}_{O_2/H_2O} = +1.23 \, V \) - \( E^{\circ}_{S_2O_8^{2-}/SO_4^{2-}} = +2.05 \, V \) - \( E^{\circ}_{Br_2/Br^-} = +1.09 \, V \) - \( E^{\circ}_{Au^{3+}/Au} = +1.40 \, V \) ### Step 4: Identify the highest value From the comparison: - The highest standard reduction potential is \( +2.05 \, V \) for \( S_2O_8^{2-}/SO_4^{2-} \). ### Step 5: Conclusion Since \( S_2O_8^{2-} \) has the highest standard reduction potential, it is the strongest oxidizing agent among the given options. ### Final Answer The strongest oxidizing agent is \( S_2O_8^{2-} \). ---
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