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The peptide that gives positive ceric am...

The peptide that gives positive ceric ammonimum nitrate and carbylamine tests is:

A

Ser-Lys

B

Gln-Asp

C

Lys-Asp

D

Asp-Gln

Text Solution

AI Generated Solution

The correct Answer is:
To determine the peptide that gives positive ceric ammonium nitrate and carbylamine tests, we need to analyze the functional groups present in the given peptides. ### Step-by-Step Solution: 1. **Understanding the Tests:** - **Ceric Ammonium Nitrate Test:** This test is positive for compounds containing alcohol (-OH) or phenolic groups. - **Carbylamine Test:** This test is positive for primary amines (1° amines), which have the structure -NH2. 2. **Analyzing the Peptides:** - **Option A: Serine (Ser)** - Functional Group: Serine has a hydroxyl group (-OH) which makes it capable of giving a positive ceric ammonium nitrate test. - **Option B: Lysine (Lys)** - Functional Group: Lysine has an amino group (-NH2), which qualifies it as a primary amine. Therefore, it can give a positive carbylamine test. - **Option C: Glutamine (Gln)** - Functional Group: Glutamine has an amide group (C=O, NH2) and does not have a primary amine that would give a positive carbylamine test. - **Option D: Aspartic Acid (Asp)** - Functional Group: Aspartic acid has a carboxylic acid group (-COOH) and does not contain a primary amine, thus it cannot give a positive carbylamine test. 3. **Conclusion:** - Since Serine gives a positive ceric ammonium nitrate test and Lysine gives a positive carbylamine test, the peptide that gives both tests is **Lysine** (Option A). ### Final Answer: The peptide that gives positive ceric ammonium nitrate and carbylamine tests is **Lysine (Option A)**.
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